Spontaneous magnetization is the appearance of an ordered spin state (magnetization) at zero applied magnetic field in a ferromagnetic or ferrimagnetic material below a critical point called the Curie temperature or TC.
Heated to temperatures above TC, ferromagnetic materials become paramagnetic and their magnetic behavior is dominated by spin waves or magnons, which are boson collective excitations with energies in the meV range. The magnetization that occurs below TC is a famous example of the "spontaneous" breaking of a global symmetry, a phenomenon that is described by Goldstone's theorem. The term "symmetry breaking" refers to the choice of a magnetization direction by the spins, which have spherical symmetry above TC, but a preferred axis (the magnetization direction) below TC.
To a first order approximation, the temperature dependence of spontaneous magnetization at low temperatures is given by Bloch's law:
where M(0) is the spontaneous magnetization at absolute zero. The decrease in spontaneous magnetization at higher temperatures is caused by the increasing excitation of spin waves. In a particle description, the spin waves correspond to magnons, which are the massless Goldstone bosons corresponding to the broken symmetry. This is exactly true for an isotropic magnet.
Magnetic anisotropy, that is the existence of an easy direction along which the moments align spontaneously in the crystal, corresponds however to "massive" magnons. This is a way of saying that they cost a minimum amount of energy to excite, hence they are very unlikely to be excited as . Hence the magnetization of an anisotropic magnet is harder to destroy at low temperature and the temperature dependence of the magnetization deviates accordingly from the Bloch's law. All real magnets are anisotropic to some extent.
Near the Curie temperature,
An empirical interpolation of the two regimes is given by
it is easy to check two limits of this interpolation that follow laws similar to the Bloch law, for , and the critical behavior, for , respectively.