Radius of gyration
Radius of gyration or gyradius of a body about an axis of rotation is defined as the radial distance of a point, from the axis of rotation at which, if whole mass of the body is assumed to be concentrated, its moment of inertia about the given axis would be the same as with its actual distribution of mass.
Mathematically the radius of gyration is the root mean square distance of the object's parts from either its center of mass or a given axis, depending on the relevant application. It is actually the perpendicular distance from point mass to the axis of rotation.
Suppose a body consists of particles each of mass . Let be their perpendicular distances from the axis of rotation. Then, the moment of inertia of the body about the axis of rotation is
If all the masses are the same (), then the moment of inertia is .
Since ( being the total mass of the body),
From the above equations, we have
Radius of gyration is the root mean square distance of particles from axis formula
Therefore, the radius of gyration of a body about a given axis may also be defined as the root mean square distance of the various particles of the body from the axis of rotation.
Applications in structural engineering
In structural engineering, the two-dimensional radius of gyration is used to describe the distribution of cross sectional area in a column around its centroidal axis with the mass of the body. The radius of gyration is given by the following formula:
Where is the second moment of area and is the total cross-sectional area.
The gyration radius is useful in estimating the stiffness of a column. If the principal moments of the two-dimensional gyration tensor are not equal, the column will tend to buckle around the axis with the smaller principal moment. For example, a column with an elliptical cross-section will tend to buckle in the direction of the smaller semiaxis.
In engineering, where continuous bodies of matter are generally the objects of study, the radius of gyration is usually calculated as an integral.
Applications in mechanics
The radius of gyration about a given axis () can be computed in terms of the mass moment of inertia around that axis, and the total mass m;
where is the mean position of the monomers. As detailed below, the radius of gyration is also proportional to the root mean square distance between the monomers:
As a third method, the radius of gyration can also be computed by summing the principal moments of the gyration tensor.
Since the chain conformations of a polymer sample are quasi infinite in number and constantly change over time, the "radius of gyration" discussed in polymer physics must usually be understood as a mean over all polymer molecules of the sample and over time. That is, the radius of gyration which is measured as an average over time or ensemble:
where the angular brackets denote the ensemble average.
An entropically governed polymer chain (i.e. in so called theta conditions) follows a random walk in three dimensions. The radius of gyration for this case is given by
Note that although represents the contour length of the polymer, is strongly dependent of polymer stiffness and can vary over orders of magnitude. is reduced accordingly.
One reason that the radius of gyration is an interesting property is that it can be determined experimentally with static light scattering as well as with small angle neutron- and x-ray scattering. This allows theoretical polymer physicists to check their models against reality. The hydrodynamic radius is numerically similar, and can be measured with Dynamic Light Scattering (DLS).
Derivation of identity
To show that the two definitions of are identical, we first multiply out the summand in the first definition:
Carrying out the summation over the last two terms and using the definition of gives the formula
- Stepto, R.; Chang, T.; Kratochvíl, P.; Hess, M.; Horie, K.; Sato, T.; Vohlídal, J. (2015). "Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)" (PDF). Pure Appl Chem. 87 (1): 71. doi:10.1515/pac-2013-0201.
- See for example Goldstein, Herbert (1950), Classical Mechanics (1st ed.), Reading, Massachusetts: Addison-Wesley Publishing Company equation 5-30
- Fixman, Marshall (1962). "Radius of Gyration of Polymer Chains". The Journal of Chemical Physics. 36 (2): 306–310. Bibcode:1962JChPh..36..306F. doi:10.1063/1.1732501.
- Grosberg AY and Khokhlov AR. (1994) Statistical Physics of Macromolecules (translated by Atanov YA), AIP Press. ISBN 1-56396-071-0
- Flory PJ. (1953) Principles of Polymer Chemistry, Cornell University, pp. 428-429 (Appendix C of Chapter X).