Octahedral symmetry
A regular octahedron has 24 rotational (or orientationpreserving) symmetries, and 48 symmetries altogether. These include transformations that combine a reflection and a rotation. A cube has the same set of symmetries, since it is the polyhedron that is dual to an octahedron.
Involutional symmetry C_{s}, (*) [ ] = 
Cyclic symmetry C_{nv}, (*nn) [n] = 
Dihedral symmetry D_{nh}, (*n22) [n,2] =  
Polyhedral group, [n,3], (*n32)  

Tetrahedral symmetry T_{d}, (*332) [3,3] = 
Octahedral symmetry O_{h}, (*432) [4,3] = 
Icosahedral symmetry I_{h}, (*532) [5,3] = 
The group of orientationpreserving symmetries is S_{4}, the symmetric group or the group of permutations of four objects, since there is exactly one such symmetry for each permutation of the four pairs of opposite faces of the octahedron.
Details
Chiral and full (or achiral) octahedral symmetry are the discrete point symmetries (or equivalently, symmetries on the sphere) with the largest symmetry groups compatible with translational symmetry. They are among the crystallographic point groups of the cubic crystal system.
Elements of O  Inversions of elements of O  

identity  0  inversion  0' 
3 × rotation by 180° about a 4fold axis  7, 16, 23  3 × reflection in a plane perpendicular to a 4fold axis  7', 16', 23' 
8 × rotation by 120° about a 3fold axis  3, 4, 8, 11, 12, 15, 19, 20  8 × rotoreflection by 60°  3', 4', 8', 11', 12', 15', 19', 20' 
6 × rotation by 180° about a 2fold axis  1', 2', 5', 6', 14', 21'  6 × reflection in a plane perpendicular to a 2fold axis  1, 2, 5, 6, 14, 21 
6 × rotation by 90° about a 4fold axis  9', 10', 13', 17', 18', 22'  6 × rotoreflection by 90°  9, 10, 13, 17, 18, 22 
Examples  

A complete list can be found in the Wikiversity article. 
As the hyperoctahedral group of dimension 3 the full octahedral group is the wreath product ,
and a natural way to identify its elements is as pairs with and .
But as it is also the direct product , one can simply identify the elements of tetrahedral subgroup T_{d} as and their inversions as .
So e.g. the identity is represented as and the inversion as .
is represented as and as .
A rotoreflection is a combination of rotation and reflection.
Illustration of rotoreflections  

 

Chiral octahedral symmetry
Gyration axes  

C_{4}  C_{3}  C_{2} 
3  4  6 
O, 432, or [4,3]^{+} of order 24, is chiral octahedral symmetry or rotational octahedral symmetry . This group is like chiral tetrahedral symmetry T, but the C_{2} axes are now C_{4} axes, and additionally there are 6 C_{2} axes, through the midpoints of the edges of the cube. T_{d} and O are isomorphic as abstract groups: they both correspond to S_{4}, the symmetric group on 4 objects. T_{d} is the union of T and the set obtained by combining each element of O \ T with inversion. O is the rotation group of the cube and the regular octahedron.
Orthogonal projection  Stereographic projection  

2fold  4fold  3fold  2fold 
Full octahedral symmetry
O_{h}, *432, [4,3], or m3m of order 48  achiral octahedral symmetry or full octahedral symmetry. This group has the same rotation axes as O, but with mirror planes, comprising both the mirror planes of T_{d} and T_{h}. This group is isomorphic to S_{4}.C_{2}, and is the full symmetry group of the cube and octahedron. It is the hyperoctahedral group for n = 3. See also the isometries of the cube.
With the 4fold axes as coordinate axes, a fundamental domain of O_{h} is given by 0 ≤ x ≤ y ≤ z. An object with this symmetry is characterized by the part of the object in the fundamental domain, for example the cube is given by z = 1, and the octahedron by x + y + z = 1 (or the corresponding inequalities, to get the solid instead of the surface). ax + by + cz = 1 gives a polyhedron with 48 faces, e.g. the disdyakis dodecahedron.
Faces are 8by8 combined to larger faces for a = b = 0 (cube) and 6by6 for a = b = c (octahedron).
The 9 mirror lines of full octahedral symmetry can be divided into two subgroups of 3 and 6 (drawn in purple and red), representing in two orthogonal subsymmetries: D_{2h}, and T_{d}. D_{2h} symmetry can be doubled to D_{4h} by restoring 2 mirrors from one of three orientations.
Octahedral symmetry and reflective subgroups  



Rotation matrices
Take the set of all 3x3 permutation matrices and assign a + sign or a  sign to each of the three 1s. There are 6 matrices x 8 sign permutations = 48 matrices in total giving the full octahedral group. There are exactly 24 matrices with determinant = +1 and these are the rotation matrices of the chiral octahedral group. The other 24 matrices correspond to a reflection or inversion.
Three reflectional generator matices are needed for octahedral symmetry, which represent the three mirrors of a CoxeterDynkin diagram. The product of the reflections produce 3 rotational generators.
Reflections  Rotations  

Name  R_{0}  R_{1}  R_{2}  R_{0}R_{1}  R_{1}R_{2}  R_{0}R_{2} 
Group  
Order  2  2  2  4  3  2 
Matrix 






Subgroups of full octahedral symmetry


Schoe.  Coxeter  Orb.  HM  Structure  Cyc.  Order  Index  

O_{h}  [4,3]  *432  m3m  S_{4}×S_{2}  48  1  
T_{d}  [3,3]  *332  43m  S_{4}  24  2  
D_{4h}  [2,4]  *224  4/mmm  Dih_{1}×Dih_{4}  16  3  
D_{2h}  [2,2]  *222  mmm  Dih_{1}^{3}=Dih_{1}×Dih_{2}  8  6  
C_{4v}  [4]  *44  4mm  Dih_{4}  8  6  
C_{3v}  [3]  *33  3m  Dih_{3}=S_{3}  6  8  
C_{2v}  [2]  *22  mm2  Dih_{2}  4  12  
C_{s}=C_{1v}  [ ]  *  2 or m  Dih_{1}  2  24  
T_{h}  [3^{+},4]  3*2  m3  A_{4}×S_{2}  24  2  
C_{4h}  [4^{+},2]  4*  4/m  Z_{4}×Dih_{1}  8  6  
D_{3d}  [2^{+},6]  2*3  3m  Dih_{6}=Z_{2}×Dih_{3}  12  4  
D_{2d}  [2^{+},4]  2*2  42m  Dih_{4}  8  6  
C_{2h} = D_{1d}  [2^{+},2]  2*  2/m  Z_{2}×Dih_{1}  4  12  
S_{6}  [2^{+},6^{+}]  3×  3  Z_{6}=Z_{2}×Z_{3}  6  8  
S_{4}  [2^{+},4^{+}]  2×  8  Z_{4}  4  12  
S_{2}  [2^{+},2^{+}]  ×  1  S_{2}  2  24  
O  [4,3]^{+}  432  432  S_{4}  24  2  
T  [3,3]^{+}  332  23  A_{4}  12  4  
D_{4}  [2,4]^{+}  224  422  Dih_{4}  8  6  
D_{3}  [2,3]^{+}  223  322  Dih_{3}=S_{3}  6  8  
D_{2}  [2,2]^{+}  222  222  Dih_{2}=Z_{2}^{2}  4  12  
C_{4}  [4]^{+}  44  4  Z_{4}  4  12  
C_{3}  [3]^{+}  33  3  Z_{3}=A_{3}  3  16  
C_{2}  [2]^{+}  22  2  Z_{2}  2  24  
C_{1}  [ ]^{+}  11  1  Z_{1}  1  48 
Octahedral subgroups in Coxeter notation[1] 
The isometries of the cube
(To be integrated in the rest of the text.)
The cube has 48 isometries (symmetry elements), forming the symmetry group O_{h}, isomorphic to S_{4} × C_{2}. They can be categorized as follows:
 O (the identity and 23 proper rotations) with the following conjugacy classes (in parentheses are given the permutations of the body diagonals and the unit quaternion representation):
 identity (identity; 1)
 rotation about an axis from the center of a face to the center of the opposite face by an angle of 90°: 3 axes, 2 per axis, together 6 ((1 2 3 4), etc.; ((1±i)/√2, etc.)
 ditto by an angle of 180°: 3 axes, 1 per axis, together 3 ((1 2) (3 4), etc.; i,j,k)
 rotation about an axis from the center of an edge to the center of the opposite edge by an angle of 180°: 6 axes, 1 per axis, together 6 ((1 2), etc.; ((i±j)/√2, etc.)
 rotation about a body diagonal by an angle of 120°: 4 axes, 2 per axis, together 8 ((1 2 3), etc.; (1±i±j±k)/2)
 The same with inversion (x is mapped to −x) (also 24 isometries). Note that rotation by an angle of 180° about an axis combined with inversion is just reflection in the perpendicular plane. The combination of inversion and rotation about a body diagonal by an angle of 120° is rotation about the body diagonal by an angle of 60°, combined with reflection in the perpendicular plane (the rotation itself does not map the cube to itself; the intersection of the reflection plane with the cube is a regular hexagon).
An isometry of the cube can be identified in various ways:
 by the faces three given adjacent faces (say 1, 2, and 3 on a die) are mapped to
 by the image of a cube with on one face a nonsymmetric marking: the face with the marking, whether it is normal or a mirror image, and the orientation
 by a permutation of the four body diagonals (each of the 24 permutations is possible), combined with a toggle for inversion of the cube, or not
For cubes with colors or markings (like dice have), the symmetry group is a subgroup of O_{h}.
Examples:
 C_{4v}, [4], (*422): if one face has a different color (or two opposite faces have colors different from each other and from the other four), the cube has 8 isometries, like a square has in 2D.
 D_{2h}, [2,2], (*222): if opposite faces have the same colors, different for each set of two, the cube has 8 isometries, like a cuboid.
 D_{4h}, [4,2], (*422): if two opposite faces have the same color, and all other faces have one different color, the cube has 16 isometries, like a square prism (square box).
 C_{2v}, [2], (*22):
 if two adjacent faces have the same color, and all other faces have one different color, the cube has 4 isometries.
 if three faces, of which two opposite to each other, have one color and the other three one other color, the cube has 4 isometries.
 if two opposite faces have the same color, and two other opposite faces also, and the last two have different colors, the cube has 4 isometries, like a piece of blank paper with a shape with a mirror symmetry.
 C_{s}, [ ], (*):
 if two adjacent faces have colors different from each other, and the other four have a third color, the cube has 2 isometries.
 if two opposite faces have the same color, and all other faces have different colors, the cube has 2 isometries, like an asymmetric piece of blank paper.
 C_{3v}, [3], (*33): if three faces, of which none opposite to each other, have one color and the other three one other color, the cube has 6 isometries.
For some larger subgroups a cube with that group as symmetry group is not possible with just coloring whole faces. One has to draw some pattern on the faces.
Examples:
 D_{2d}, [2^{+},4], (2*2): if one face has a line segment dividing the face into two equal rectangles, and the opposite has the same in perpendicular direction, the cube has 8 isometries; there is a symmetry plane and 2fold rotational symmetry with an axis at an angle of 45° to that plane, and, as a result, there is also another symmetry plane perpendicular to the first, and another axis of 2fold rotational symmetry perpendicular to the first.
 T_{h}, [3^{+},4], (3*2): if each face has a line segment dividing the face into two equal rectangles, such that the line segments of adjacent faces do not meet at the edge, the cube has 24 isometries: the even permutations of the body diagonals and the same combined with inversion (x is mapped to −x).
 T_{d}, [3,3], (*332): if the cube consists of eight smaller cubes, four white and four black, put together alternatingly in all three standard directions, the cube has again 24 isometries: this time the even permutations of the body diagonals and the inverses of the other proper rotations.
 T, [3,3]^{+}, (332): if each face has the same pattern with 2fold rotational symmetry, say the letter S, such that at all edges a top of one S meets a side of the other S, the cube has 12 isometries: the even permutations of the body diagonals.
The full symmetry of the cube, O_{h}, [4,3], (*432), is preserved if and only if all faces have the same pattern such that the full symmetry of the square is preserved, with for the square a symmetry group, Dih_{4}, [4], of order 8.
The full symmetry of the cube under proper rotations, O, [4,3]^{+}, (432), is preserved if and only if all faces have the same pattern with 4fold rotational symmetry, C_{4}, [4]^{+}.
Octahedral symmetry of the Bolza surface
In Riemann surface theory, the Bolza surface, sometimes called the Bolza curve, is obtained as the ramified double cover of the Riemann sphere, with ramification locus at the set of vertices of the regular inscribed octahedron. Its automorphism group includes the hyperelliptic involution which flips the two sheets of the cover. The quotient by the order 2 subgroup generated by the hyperelliptic involution yields precisely the group of symmetries of the octahedron. Among the many remarkable properties of the Bolza surface is the fact that it maximizes the systole among all genus 2 hyperbolic surfaces.
Solids with octahedral chiral symmetry
Class  Name  Picture  Faces  Edges  Vertices  Dual name  Picture 

Archimedean solid (Catalan solid) 
snub cube  38  60  24  pentagonal icositetrahedron 
Solids with full octahedral symmetry
Class  Name  Picture  Faces  Edges  Vertices  Dual name  Picture 

Platonic solid  Cube  6  12  8  Octahedron  
Archimedean solid (dual Catalan solid) 
Cuboctahedron  14  24  12  Rhombic dodecahedron  
Truncated cube  14  36  24  Triakis octahedron  
Truncated octahedron  14  36  24  Tetrakis hexahedron  
Rhombicuboctahedron  26  48  24  Deltoidal icositetrahedron  
Truncated cuboctahedron  26  72  48  Disdyakis dodecahedron  
Regular compound polyhedron 
Stella octangula  8  12  8  Selfdual  
Cube and octahedron  14  24  14  Selfdual 
See also
References
 John Conway, The Symmetries of Things, Fig 20.8, p280
 Peter R. Cromwell, Polyhedra (1997), p. 295
 The Symmetries of Things 2008, John H. Conway, Heidi Burgiel, Chaim GoodmanStrass, ISBN 9781568812205
 Kaleidoscopes: Selected Writings of H.S.M. Coxeter, edited by F. Arthur Sherk, Peter McMullen, Anthony C. Thompson, Asia Ivic Weiss, WileyInterscience Publication, 1995, ISBN 9780471010036
 N.W. Johnson: Geometries and Transformations, (2018) ISBN 9781107103405 Chapter 11: Finite symmetry groups, 11.5 Spherical Coxeter groups