The London equations are constitutive relations for superconductors. They relate current to electromagnetic fields in and around a superconductor, as well as Ohm's law is the simplest constitutive relation for an ordinary conductor. Arguably the simplest meaningful description of superconducting phenomena, they form the genesis of almost any modern introductory text on the subject. A major triumph of the equations is their ability to explain the Meissner effect, wherein a material exponentially expels all internal magnetic fields as it crosses the superconducting threshold.
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There are two London equations when expressed in terms of measurable fields:
Here is the (superconducting) current density, E and B are respectively the electric and magnetic fields within the superconductor, is the charge of an electron & proton, is electron mass, and is a phenomenological constant loosely associated with a number density of superconducting carriers.
On the other hand, if one is willing to abstract away slightly, both the expressions above can more neatly be written in terms of a single "London Equation" in terms of the vector potential A:
The last equation suffers from only the disadvantage that it is not gauge invariant, but is true only in the Coulomb gauge, where the divergence of A is zero. This equation holds for magnetic fields that vary slowly in space.
London penetration depth
If the second of London's equations is manipulated by applying Ampere's law,
then it can be turned into the Helmholtz equation for magnetic field:
where the inverse of the laplacian eigenvalue:
For example, consider a superconductor within free space where the magnetic field outside the superconductor is a constant value pointed parallel to the superconducting boundary plane in the z direction. If x leads perpendicular to the boundary then the solution inside the superconductor may be shown to be
From here the physical meaning of the London penetration depth can perhaps most easily be discerned.
Rationale for the London equations
While it is important to note that the above equations cannot be formally derived, the Londons did follow a certain intuitive logic in the formulation of their theory. Substances across a stunningly wide range of composition behave roughly according to Ohm's law, which states that current is proportional to electric field. However, such a linear relationship is impossible in a superconductor for, almost by definition, the electrons in a superconductor flow with no resistance whatsoever. To this end, the London brothers imagined electrons as if they were free electrons under the influence of a uniform external electric field. According to the Lorentz force law
these electrons should encounter a uniform force, and thus they should in fact accelerate uniformly. This is precisely what the first London equation states.
To obtain the second equation, take the curl of the first London equation and apply Faraday's law,
As it currently stands, this equation permits both constant and exponentially decaying solutions. The Londons recognized from the Meissner effect that constant nonzero solutions were nonphysical, and thus postulated that not only was the time derivative of the above expression equal to zero, but also that the expression in the parentheses must be identically zero. This results in the second London equation.
Canonical momentum arguments
Taking this expression from a classical description to a quantum mechanical one, we must replace values j and v by the expectation values of their operators. The velocity operator
is defined by dividing the gauge-invariant, kinematic momentum operator by the particle mass m. Note we are using as the electron charge. We may then make this replacement in the equation above. However, an important assumption from the microscopic theory of superconductivity is that the superconducting state of a system is the ground state, and according to a theorem of Bloch's, in such a state the canonical momentum p is zero. This leaves
which is the London equation according to the second formulation above.
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- (The displacement is ignored because it is assumed that electric field only varies slowly with respect to time, and the term is already suppressed by a factor of c.)
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