Heavy metals are generally defined as metals with relatively high densities, atomic weights, or atomic numbers. The criteria used, and whether metalloids are included, vary depending on the author and context. In metallurgy, for example, a heavy metal may be defined on the basis of density, whereas in physics the distinguishing criterion might be atomic number, while a chemist would likely be more concerned with chemical behaviour. More specific definitions have been published, but none of these have been widely accepted. The definitions surveyed in this article encompass up to 96 out of the 118 known chemical elements; only mercury, lead and bismuth meet all of them. Despite this lack of agreement, the term (plural or singular) is widely used in science. A density of more than 5 g/cm3 is sometimes quoted as a commonly used criterion and is used in the body of this article.
|Part of a series on the|
The earliest known metals—common metals such as iron, copper, and tin, and precious metals such as silver, gold, and platinum—are heavy metals. From 1809 onward, light metals, such as magnesium, aluminium, and titanium, were discovered, as well as less well-known heavy metals including gallium, thallium, and hafnium.
Some heavy metals are either essential nutrients (typically iron, cobalt, and zinc), or relatively harmless (such as ruthenium, silver, and indium), but can be toxic in larger amounts or certain forms. Other heavy metals, such as cadmium, mercury, and lead, are highly poisonous. Potential sources of heavy metal poisoning include mining, tailings, industrial wastes, agricultural runoff, occupational exposure, paints and treated timber.
Physical and chemical characterisations of heavy metals need to be treated with caution, as the metals involved are not always consistently defined. As well as being relatively dense, heavy metals tend to be less reactive than lighter metals and have far fewer soluble sulfides and hydroxides. While it is relatively easy to distinguish a heavy metal such as tungsten from a lighter metal such as sodium, a few heavy metals, such as zinc, mercury, and lead, have some of the characteristics of lighter metals, and, lighter metals such as beryllium, scandium, and titanium, have some of the characteristics of heavier metals.
Heavy metals are relatively scarce in the Earth's crust but are present in many aspects of modern life. They are used in, for example, golf clubs, cars, antiseptics, self-cleaning ovens, plastics, solar panels, mobile phones, and particle accelerators.
|Heat map of heavy metals in the periodic table|
|This table shows the number of heavy metal criteria met by each metal, out of the ten criteria listed in this section i.e. two based on density, three on atomic weight, two on atomic number, and three on chemical behaviour. It illustrates the lack of agreement surrounding the concept, with the possible exception of mercury, lead and bismuth.|
Six elements near the end of periods (rows) 4 to 7 sometimes considered metalloids are treated here as metals: they are germanium (Ge), arsenic (As), selenium (Se), antimony (Sb), tellurium (Te), and astatine (At). Oganesson (Og) is treated as a nonmetal.
There is no widely agreed criterion-based definition of a heavy metal. Different meanings may be attached to the term, depending on the context. In metallurgy, for example, a heavy metal may be defined on the basis of density, whereas in physics the distinguishing criterion might be atomic number, and a chemist or biologist would likely be more concerned with chemical behaviour.
Density criteria range from above 3.5 g/cm3 to above 7 g/cm3. Atomic weight definitions can range from greater than sodium (atomic weight 22.98); greater than 40 (excluding s- and f-block metals, hence starting with scandium); or more than 200, i.e. from mercury onwards. Atomic numbers of heavy metals are generally given as greater than 20 (calcium); sometimes this is capped at 92 (uranium). Definitions based on atomic number have been criticised for including metals with low densities. For example, rubidium in group (column) 1 of the periodic table has an atomic number of 37 but a density of only 1.532 g/cm3, which is below the threshold figure used by other authors. The same problem may occur with atomic weight based definitions.
The United States Pharmacopeia includes a test for heavy metals that involves precipitating metallic impurities as their coloured sulfides." In 1997, Stephen Hawkes, a chemistry professor writing in the context of fifty years' experience with the term, said it applied to "metals with insoluble sulfides and hydroxides, whose salts produce colored solutions in water and whose complexes are usually colored". On the basis of the metals he had seen referred to as heavy metals, he suggested it would useful to define them as (in general) all the metals in periodic table columns 3 to 16 that are in row 4 or greater, in other words, the transition metals and post-transition metals. The lanthanides satisfy Hawkes' three-part description; the status of the actinides is not completely settled.
In biochemistry, heavy metals are sometimes defined—on the basis of the Lewis acid (electronic pair acceptor) behaviour of their ions in aqueous solution—as class B and borderline metals. In this scheme, class A metal ions prefer oxygen donors; class B ions prefer nitrogen or sulfur donors; and borderline or ambivalent ions show either class A or B characteristics, depending on the circumstances. Class A metals, which tend to have low electronegativity and form bonds with large ionic character, are the alkali and alkaline earths, aluminium, the group 3 metals, and the lanthanides and actinides. Class B metals, which tend to have higher electronegativity and form bonds with considerable covalent character, are mainly the heavier transition and post-transition metals. Borderline metals largely comprise the lighter transition and post-transition metals (plus arsenic and antimony). The distinction between the class A metals and the other two categories is sharp. A frequently cited proposal to use these classification categories instead of the more evocative name heavy metal has not been widely adopted.
List of heavy metals based on density
A density of more than 5 g/cm3 is sometimes mentioned as a common heavy metal defining factor and, in the absence of a unanimous definition, is used to populate this list and (unless otherwise stated) guide the remainder of the article. Metalloids meeting the applicable criteria–arsenic and antimony for example—are sometimes counted as heavy metals, particularly in environmental chemistry, as is the case here. Selenium (density 4.8 g/cm3) is also included in the list. It falls marginally short of the density criterion and is less commonly recognised as a metalloid but has a waterborne chemistry similar in some respects to that of arsenic and antimony. Other metals sometimes classified or treated as "heavy" metals, such as beryllium (density 1.8 g/cm3), aluminium (2.7 g/cm3), calcium (1.55 g/cm3), and barium (3.6 g/cm3) are here treated as light metals and, in general, are not further considered.
|Produced mainly by commercial mining (informally classified by economic significance)|
|Produced mainly by artificial transmutation (informally classified by stability)|
Origins and use of the term
The heaviness of naturally occurring metals such as gold, copper, and iron may have been noticed in prehistory and, in light of their malleability, led to the first attempts to craft metal ornaments, tools, and weapons. All metals discovered from then until 1809 had relatively high densities; their heaviness was regarded as a singularly distinguishing criterion.
From 1809 onwards, light metals such as sodium, potassium, and strontium were isolated. Their low densities challenged conventional wisdom and it was proposed to refer to them as metalloids (meaning "resembling metals in form or appearance"). This suggestion was ignored; the new elements came to be recognised as metals, and the term metalloid was then used to refer to nonmetallic elements and, later, elements that were hard to describe as either metals or nonmetals.
An early use of the term "heavy metal" dates from 1817, when the German chemist Leopold Gmelin divided the elements into nonmetals, light metals, and heavy metals. Light metals had densities of 0.860–5.0 g/cm3; heavy metals 5.308–22.000. The term later became associated with elements of high atomic weight or high atomic number. It is sometimes used interchangeably with the term heavy element. For example, in discussing the history of nuclear chemistry, Magee notes that the actinides were once thought to represent a new heavy element transition group whereas Seaborg and co-workers "favoured ... a heavy metal rare-earth like series ...". In astronomy, however, a heavy element is any element heavier than hydrogen and helium.
In 2002, Scottish toxicologist John Duffus reviewed the definitions used over the previous 60 years and concluded they were so diverse as to effectively render the term meaningless. Along with this finding, the heavy metal status of some metals is occasionally challenged on the grounds that they are too light, or are involved in biological processes, or rarely constitute environmental hazards. Examples include scandium (too light); vanadium to zinc (biological processes); and rhodium, indium, and osmium (too rare).
Despite its questionable meaning, the term heavy metal appears regularly in scientific literature. A 2010 study found that it had been increasingly used and seemed to have become part of the language of science. It is said to be an acceptable term, given its convenience and familiarity, as long as it is accompanied by a strict definition. The counterparts to the heavy metals, the light metals, are alluded to by The Minerals, Metals and Materials Society as including "aluminium, magnesium, beryllium, titanium, lithium, and other reactive metals." The named metals have densities of 0.534 to 4.54 g/cm3.
Trace amounts of some heavy metals, mostly in period 4, are required for certain biological processes. These are iron and copper (oxygen and electron transport); cobalt (complex syntheses and cell metabolism); zinc (hydroxylation); vanadium and manganese (enzyme regulation or functioning); chromium (glucose utilisation); nickel (cell growth); arsenic (metabolic growth in some animals and possibly in humans) and selenium (antioxidant functioning and hormone production). Periods 5 and 6 contain fewer essential heavy metals, consistent with the general pattern that heavier elements tend to be less abundant and that scarcer elements are less likely to be nutritionally essential. In period 5, molybdenum is required for the catalysis of redox reactions; cadmium is used by some marine diatoms for the same purpose; and tin may be required for growth in a few species. In period 6, tungsten is required by some archaea and bacteria for metabolic processes. A deficiency of any of these period 4–6 essential heavy metals may increase susceptibility to heavy metal poisoning (conversely, an excess may also have adverse biological effects). An average 70 kg human body is about 0.01% heavy metals (~7 g, equivalent to the weight of two dried peas, with iron at 4 g, zinc at 2.5 g, and lead at 0.12 g comprising the three main constituents), 2% light metals (~1.4 kg, the weight of a bottle of wine) and nearly 98% nonmetals (mostly water).
A few non-essential heavy metals have been observed to have biological effects. Gallium, germanium (a metalloid), indium, and most lanthanides can stimulate metabolism, and titanium promotes growth in plants (though it is not always considered a heavy metal).
- The focus of this section is mainly on the more serious toxic effects of heavy metals, including cancer, brain damage or death, rather than the harm they may cause to one more of the skin, lungs, stomach, kidneys, liver, or heart. For more specific information see Metal toxicity, Toxic heavy metal, or the articles on individual elements or compounds.
Environmental heavy metals
Chromium, arsenic, cadmium, mercury, and lead have the greatest potential to cause harm on account of their extensive use, the toxicity of some of their combined or elemental forms, and their widespread distribution in the environment. Hexavalent chromium, for example, is highly toxic as are mercury vapour and many mercury compounds. These five elements have a strong affinity for sulfur; in the human body they usually bind, via thiol groups (–SH), to enzymes responsible for controlling the speed of metabolic reactions. The resulting sulfur-metal bonds inhibit the proper functioning of the enzymes involved; human health deteriorates, sometimes fatally. Chromium (in its hexavalent form) and arsenic are carcinogens; cadmium causes a degenerative bone disease; and mercury and lead damage the central nervous system.
Lead is the most prevalent heavy metal contaminant. Levels in the aquatic environments of industrialised societies have been estimated to be two to three times those of pre-industrial levels. As a component of tetraethyl lead, (CH
4Pb, it was used extensively in gasoline during the 1930s–1970s. Although the use of leaded gasoline was largely phased out in North America by 1996, soils next to roads built before this time retain high lead concentrations. Later research demonstrated a statistically significant correlation between the usage rate of leaded gasoline and violent crime in the United States; taking into account a 22-year time lag (for the average age of violent criminals), the violent crime curve virtually tracked the lead exposure curve.
Other heavy metals noted for their potentially hazardous nature, usually as toxic environmental pollutants, include manganese (central nervous system damage); cobalt and nickel (carcinogens); copper, zinc, selenium and silver (endocrine disruption, congenital disorders, or general toxic effects in fish, plants, birds, or other aquatic organisms); tin, as organotin (central nervous system damage); antimony (a suspected carcinogen); and thallium (central nervous system damage).
Nutritionally essential heavy metals
Heavy metals essential for life can be toxic if taken in excess; some have notably toxic forms. Vanadium pentoxide (V2O5) is carcinogenic in animals and, when inhaled, causes DNA damage. The purple permanganate ion MnO–
4 is a liver and kidney poison. Ingesting more than 0.5 grams of iron can induce cardiac collapse; such overdoses most commonly occur in children and may result in death within 24 hours. Nickel carbonyl (Ni(CO)4), at 30 parts per million, can cause respiratory failure, brain damage and death. Imbibing a gram or more of copper sulfate (CuSO4) can be fatal; survivors may be left with major organ damage. More than five milligrams of selenium is highly toxic; this is roughly ten times the 0.45 milligram recommended maximum daily intake; long-term poisoning can have paralytic effects.
Other heavy metals
A few other non-essential heavy metals have one or more toxic forms. Kidney failure and fatalities have been recorded arising from the ingestion of germanium dietary supplements (~15 to 300 g in total consumed over a period of two months to three years). Exposure to osmium tetroxide (OsO4) may cause permanent eye damage and can lead to respiratory failure and death. Indium salts are toxic if more than few milligrams are ingested and will affect the kidneys, liver, and heart. Cisplatin (PtCl2(NH3)2), which is an important drug used to kill cancer cells, is also a kidney and nerve poison. Bismuth compounds can cause liver damage if taken in excess; insoluble uranium compounds, as well as the dangerous radiation they emit, can cause permanent kidney damage.
Heavy metals can degrade air, water, and soil quality, and subsequently cause health issues in plants, animals, and people, when they become concentrated as a result of industrial activities. Common sources of heavy metals in this context include mining and industrial wastes; vehicle emissions; lead-acid batteries; fertilisers; paints; and treated timber; aging water supply infrastructure; and microplastics floating in the world's oceans. Recent examples of heavy metal contamination and health risks include the occurrence of Minamata disease, in Japan (1932–1968; lawsuits ongoing as of 2016); the Bento Rodrigues dam disaster in Brazil, and high levels of lead in drinking water supplied to the residents of Flint, Michigan, in the north-east of the United States.
Formation, abundance, occurrence, and extraction
|Heavy metals in the Earth's crust:|
|abundance and main occurrence or source|
Most abundant (56300 ppm by weight)
Rare (0.01–0.99 ppm)
Abundant (100–999 ppm)
Very rare (0.0001–0.0099 ppm)
Uncommon (1–99 ppm)
|Heavy metals left of the dividing line occur (or are sourced) mainly as lithophiles; those to the right, as chalcophiles except gold (a siderophile) and tin (a lithophile).|
Heavy metals up to the vicinity of iron (in the periodic table) are largely made via stellar nucleosynthesis. In this process, lighter elements from hydrogen to silicon undergo successive fusion reactions inside stars, releasing light and heat and forming heavier elements with higher atomic numbers.
Heavier heavy metals are not usually formed this way since fusion reactions involving such nuclei would consume rather than release energy. Rather, they are largely synthesised (from elements with a lower atomic number) by neutron capture, with the two main modes of this repetitive capture being the s-process and the r-process. In the s-process ("s" stands for "slow"), singular captures are separated by years or decades, allowing the less stable nuclei to beta decay, while in the r-process ("rapid"), captures happen faster than nuclei can decay. Therefore, the s-process takes a more or less clear path: for example, stable cadmium-110 nuclei are successively bombarded by free neutrons inside a star until they form cadmium-115 nuclei which are unstable and decay to form indium-115 (which is nearly stable, with a half-life 30000 times the age of the universe). These nuclei capture neutrons and form indium-116, which is unstable, and decays to form tin-116, and so on. In contrast, there is no such path in the r-process. The s-process stops at bismuth due to the short half-lives of the next two elements, polonium and astatine, which decay to bismuth or lead. The r-process is so fast it can skip this zone of instability and go on to create heavier elements such as thorium and uranium.
Heavy metals condense in planets as a result of stellar evolution and destruction processes. Stars lose much of their mass when it is ejected late in their lifetimes, and sometimes thereafter as a result of a neutron star merger, thereby increasing the abundance of elements heavier than helium in the interstellar medium. When gravitational attraction causes this matter to coalesce and collapse, new stars and planets are formed.
The Earth's crust is made of approximately 5% of heavy metals by weight, with iron comprising 95% of this quantity. Light metals (~20%) and nonmetals (~75%) make up the other 95% of the crust. Despite their overall scarcity, heavy metals can become concentrated in economically extractable quantities as a result of mountain building, erosion, or other geological processes.
Heavy metals are primarily found as lithophiles (rock-loving) or chalcophiles (ore-loving). Lithophile heavy metals are mainly f-block elements and the more reactive of the d-block elements. They have a strong affinity for oxygen and mostly exist as relatively low density silicate minerals. Chalcophile heavy metals are mainly the less reactive d-block elements, and period 4–6 p-block metals and metalloids. They are usually found in (insoluble) sulfide minerals. Being denser than the lithophiles, hence sinking lower into the crust at the time of its solidification, the chalcophiles tend to be less abundant than the lithophiles.
On the other hand, gold is a siderophile, or iron-loving element. It does not readily form compounds with either oxygen or sulfur. At the time of the Earth's formation, and as the most noble (inert) of metals, gold sank into the core due to its tendency to form high-density metallic alloys. Consequently, it is a relatively rare metal. Some other (less) noble heavy metals—molybdenum, rhenium, the platinum group metals (ruthenium, rhodium, palladium, osmium, iridium, and platinum), germanium, and tin—can be counted as siderophiles but only in terms of their primary occurrence in the Earth (core, mantle and crust), rather the crust. These metals otherwise occur in the crust, in small quantities, chiefly as chalcophiles (less so in their native form).
Concentrations of heavy metals below the crust are generally higher, with most being found in the largely iron-silicon-nickel core. Platinum, for example, comprises approximately 1 part per billion of the crust whereas its concentration in the core is thought to be nearly 6,000 times higher. Recent speculation suggests that uranium (and thorium) in the core may generate a substantial amount of the heat that drives plate tectonics and (ultimately) sustains the Earth's magnetic field.
The winning of heavy metals from their ores is a complex function of ore type, the chemical properties of the metals involved, and the economics of various extraction methods. Different countries and refineries may use different processes, including those that differ from the brief outlines listed here.
Broadly speaking, and with some exceptions, lithophile heavy metals can be extracted from their ores by electrical or chemical treatments, while chalcophile heavy metals are obtained by roasting their sulphide ores to yield the corresponding oxides, and then heating these to obtain the raw metals. Radium occurs in quantities too small to be economically mined and is instead obtained from spent nuclear fuels. The chalcophile platinum group metals (PGM) mainly occur in small (mixed) quantities with other chalcophile ores. The ores involved need to be smelted, roasted, and then leached with sulfuric acid to produce a residue of PGM. This is chemically refined to obtain the individual metals in their pure forms. Compared to other metals, PGM are expensive due to their scarcity and high production costs.
Gold, a siderophile, is most commonly recovered by dissolving the ores in which it is found in a cyanide solution. The gold forms a dicyanoaurate(I), for example: 2 Au + H2O +½ O2 + 4 KCN → 2 K[Au(CN)2] + 2 KOH. Zinc is added to the mix and, being more reactive than gold, displaces the gold: 2 K[Au(CN)2] + Zn → K2[Zn(CN)4] + 2 Au. The gold precipitates out of solution as a sludge, and is filtered off and melted.
Properties compared with light metals
Some general physical and chemical properties of light and heavy metals are summarised in the table. The comparison should be treated with caution since the terms light metal and heavy metal are not always consistently defined. Also the physical properties of hardness and tensile strength can vary widely depending on purity, grain size and pre-treatment.
|Physical properties||Light metals||Heavy metals|
|Density||Usually lower||Usually higher|
|Hardness||Tend to be soft, easily cut or bent||Most are quite hard|
|Thermal expansivity||Mostly higher||Mostly lower|
|Melting point||Mostly low||Low to very high|
|Tensile strength||Mostly lower||Mostly higher|
|Chemical properties||Light metals||Heavy metals|
|Periodic table location||Most found in groups 1 and 2||Nearly all found in groups 3 through 16|
|Abundance in Earth's crust||More abundant||Less abundant|
|Main occurrence (or source)||Lithophiles||Lithophiles or chalcophiles (Au is a siderophile)|
|Reactivity||More reactive||Less reactive|
|Sulfides||Soluble to insoluble||Extremely insoluble|
|Hydroxides||Soluble to insoluble||Generally insoluble|
|Salts||Mostly form colourless solutions in water||Mostly form coloured solutions in water|
|Complexes||Mostly colourless||Mostly coloured|
|Biological role||Include macronutrients (Na, Mg, K, Ca)||Include micronutrients (V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Mo)|
These properties make it relatively easy to distinguish a light metal like sodium from a heavy metal like tungsten, but the differences become less clear at the boundaries. Light structural metals like beryllium, scandium, and titanium have some of the characteristics of heavy metals, such as higher melting points; post-transition heavy metals like zinc, cadmium, and lead have some of the characteristics of light metals, such as being relatively soft, having lower melting points, and forming mainly colourless complexes.
Heavy metals are present in nearly all aspects of modern life. Iron may be the most common as it accounts for 90% of all refined metals. Platinum may be the most ubiquitous given it is said to be found in, or used to produce, 20% of all consumer goods.
Some common uses of heavy metals depend on the general characteristics of metals such as electrical conductivity and reflectivity or the general characteristics of heavy metals such as density, strength, and durability. Other uses depend on the characteristics of the specific element, such as their biological role as nutrients or poisons or some other specific atomic properties. Examples of such atomic properties include: partly filled d- or f- orbitals (in many of the transition, lanthanide, and actinide heavy metals) that enable the formation of coloured compounds; the capacity of most heavy metal ions (such as platinum, cerium or bismuth) to exist in different oxidation states and therefore act as catalysts; poorly overlapping 3d or 4f orbitals (in iron, cobalt, and nickel, or the lanthanide heavy metals from europium through thulium) that give rise to magnetic effects; and high atomic numbers and electron densities that underpin their nuclear science applications. Typical uses of heavy metals can be broadly grouped into the following six categories.
Weight- or density-based
Some uses of heavy metals, including in sport, mechanical engineering, military ordnance, and nuclear science, take advantage of their relatively high densities. In underwater diving, lead is used as a ballast; in handicap horse racing each horse must carry a specified lead weight, based on factors including past performance, so as to equalize the chances of the various competitors. In golf, tungsten, brass, or copper inserts in fairway clubs and irons lower the centre of gravity of the club making it easier to get the ball into the air; and golf balls with tungsten cores are claimed to have better flight characteristics. In fly fishing, sinking fly lines have a PVC coating embedded with tungsten powder, so that they sink at the required rate. In track and field sport, steel balls used in the hammer throw and shot put events are filled with lead in order to attain the minimum weight required under international rules. Tungsten was used in hammer throw balls at least up to 1980; the minimum size of the ball was increased in 1981 to eliminate the need for what was, at that time, an expensive metal (triple the cost of other hammers) not generally available in all countries. Tungsten hammers were so dense that they penetrated too deeply into the turf.
In mechanical engineering, heavy metals are used for ballast in boats, aeroplanes, and motor vehicles; or in balance weights on wheels and crankshafts, gyroscopes, and propellers, and centrifugal clutches, in situations requiring maximum weight in minimum space (for example in watch movements).
AM Russell and KL Lee
in nonferrous metals (2005, p. 16)
In military ordnance, tungsten or uranium is used in armour plating and armour piercing projectiles, as well as in nuclear weapons to increase efficiency (by reflecting neutrons and momentarily delaying the expansion of reacting materials). In the 1970s, tantalum was found to be more effective than copper in shaped charge and explosively formed anti-armour weapons on account of its higher density, allowing greater force concentration, and better deformability. Less-toxic heavy metals, such as copper, tin, tungsten, and bismuth, and probably manganese (as well as boron, a metalloid), have replaced lead and antimony in the green bullets used by some armies and in some recreational shooting munitions. Doubts have been raised about the safety (or green credentials) of tungsten.
Because denser materials absorb more radioactive emissions than lighter ones, heavy metals are useful for radiation shielding and to focus radiation beams in linear accelerators and radiotherapy applications.
Strength- or durability-based
The strength or durability of heavy metals such as chromium, iron, nickel, copper, zinc, molybdenum, tin, tungsten, and lead, as well as their alloys, makes them useful for the manufacture of artefacts such as tools, machinery, appliances, utensils, pipes, railroad tracks, buildings and bridges, automobiles, locks, furniture, ships, planes, coinage and jewellery. They are also used as alloying additives for enhancing the properties of other metals. Of the two dozen elements that have been used in the world's monetised coinage only two, carbon and aluminium, are not heavy metals. Gold, silver, and platinum are used in jewellery as are (for example) nickel, copper, indium, and cobalt in coloured gold. Low-cost jewellery and children's toys may be made, to a significant degree, of heavy metals such as chromium, nickel, cadmium, or lead.
Copper, zinc, tin, and lead are mechanically weaker metals but have useful corrosion prevention properties. While each of them will react with air, the resulting patinas of either various copper salts, zinc carbonate, tin oxide, or a mixture of lead oxide, carbonate, and sulfate, confer valuable protective properties. Copper and lead are therefore used, for example, as roofing materials; zinc acts as an anti-corrosion agent in galvanised steel; and tin serves a similar purpose on steel cans.
The workability and corrosion resistance of iron and chromium are increased by adding gadolinium; the creep resistance of nickel is improved with the addition of thorium. Tellurium is added to copper (Tellurium Copper) and steel alloys to improve their machinability; and to lead to make it harder and more acid-resistant.
Biological and chemical
The biocidal effects of some heavy metals have been known since antiquity. Platinum, osmium, copper, ruthenium, and other heavy metals, including arsenic, are used in anti-cancer treatments, or have shown potential. Antimony (anti-protozoal), bismuth (anti-ulcer), gold (anti-arthritic), and iron (anti-malarial) are also important in medicine. Copper, zinc, silver, gold, or mercury are used in antiseptic formulations; small amounts of some heavy metals are used to control algal growth in, for example, cooling towers. Depending on their intended use as fertilisers or biocides, agrochemicals may contain heavy metals such as chromium, cobalt, nickel, copper, zinc, arsenic, cadmium, mercury, or lead.
Selected heavy metals are used as catalysts in fuel processing (rhenium, for example), synthetic rubber and fibre production (bismuth), emission control devices (palladium), and in self-cleaning ovens (where cerium(IV) oxide in the walls of such ovens helps oxidise carbon-based cooking residues). In soap chemistry, heavy metals form insoluble soaps that are used in lubricating greases, paint dryers, and fungicides (apart from lithium, the alkali metals and the ammonium ion form soluble soaps).
Colouring and optics
The colours of glass, ceramic glazes, paints, pigments, and plastics are commonly produced by the inclusion of heavy metals (or their compounds) such as chromium, manganese, cobalt, copper, zinc, selenium, zirconium, molybdenum, silver, tin, praseodymium, neodymium, erbium, tungsten, iridium, gold, lead, or uranium. Tattoo inks may contain heavy metals, such as chromium, cobalt, nickel, and copper. The high reflectivity of some heavy metals is important in the construction of mirrors, including precision astronomical instruments. Headlight reflectors rely on the excellent reflectivity of a thin film of rhodium.
Electronics, magnets, and lighting
Heavy metals or their compounds can be found in electronic components, electrodes, and wiring and solar panels where they may be used as either conductors, semiconductors, or insulators. Molybdenum powder is used in circuit board inks. Ruthenium(IV) oxide coated titanium anodes are used for the industrial production of chlorine. Home electrical systems, for the most part, are wired with copper wire for its good conducting properties. Silver and gold are used in electrical and electronic devices, particularly in contact switches, as a result of their high electrical conductivity and capacity to resist or minimise the formation of impurities on their surfaces. The semiconductors cadmium telluride and gallium arsenide are used to make solar panels. Hafnium oxide, an insulator, is used as a voltage controller in microchips; tantalum oxide, another insulator, is used in capacitors in mobile phones. Heavy metals have been used in batteries for over 200 years, at least since Volta invented his copper and silver voltaic pile in 1800. Promethium, lanthanum, and mercury are further examples found in, respectively, atomic, nickel-metal hydride, and button cell batteries.
Magnets are made of heavy metals such as manganese, iron, cobalt, nickel, niobium, bismuth, praseodymium, neodymium, gadolinium, and dysprosium. Neodymium magnets are the strongest type of permanent magnet commercially available. They are key components of, for example, car door locks, starter motors, fuel pumps, and power windows.
Heavy metals are used in lighting, lasers, and light-emitting diodes (LEDs). Flat panel displays incorporate a thin film of electrically conducting indium tin oxide. Fluorescent lighting relies on mercury vapour for its operation. Ruby lasers generate deep red beams by exciting chromium atoms; the lanthanides are also extensively employed in lasers. Gallium, indium, and arsenic; and copper, iridium, and platinum are used in LEDs (the latter three in organic LEDs).
Niche uses of heavy metals with high atomic numbers occur in diagnostic imaging, electron microscopy, and nuclear science. In diagnostic imaging, heavy metals such as cobalt or tungsten make up the anode materials found in x-ray tubes. In electron microscopy, heavy metals such as lead, gold, palladium, platinum, or uranium are used to make conductive coatings and to introduce electron density into biological specimens by staining, negative staining, or vacuum deposition. In nuclear science, nuclei of heavy metals such as chromium, iron, or zinc are sometimes fired at other heavy metal targets to produce superheavy elements; heavy metals are also employed as spallation targets for the production of neutrons or radioisotopes such as astatine (using lead, bismuth, thorium, or uranium in the latter case).
- Criteria used were density: (1) above 3.5 g/cm3; (2) above 7 g/cm3; atomic weight: (3) > 22.98; (4) > 40 (excluding s- and f-block metals); (5) > 200; atomic number: (6) > 20; (7) 21–92; chemical behaviour: (8) United States Pharmacopeia; (9) Hawkes' periodic table-based definition (excluding the lanthanides and actinides); and (10) Nieboer and Richardson's biochemical classifications. Densities of the elements are mainly from Emsley. Predicted densities have been used for At, Fr and Fm–Ts. Indicative densities were derived for Fm, Md, No and Lr based on their atomic weights, estimated metallic radii, and predicted close-packed crystalline structures. Atomic weights are from Emsley, inside back cover
- Metalloids were, however, excluded from Hawkes' periodic table-based definition given he noted it was "not necessary to decide whether semimetals [i.e. metalloids] should be included as heavy metals."
- The test is not specific for any particular metals but is said to be capable of at least detecting Mo, Cu, Ag, Cd, Hg, Sn, Pb, As, Sb, and Bi. In any event, when the test uses hydrogen sulfide as the reagent it cannot detect Th, Ti, Zr, Nb, Ta, or Cr.
- Transition and post-transition metals that do not usually form coloured complexes are Sc and Y in group 3; Ag in group 11; Zn and Cd in group 12; and the metals of groups 13–16.
- Lanthanide (Ln) sulfides and hydroxides are insoluble; the latter can be obtained from aqueous solutions of Ln salts as coloured gelatinous precipitates; and Ln complexes have much the same colour as their aqua ions (the majority of which are coloured). Actinide (An) sulfides may or may not be insoluble, depending on the author. Divalent uranium monosulfide is not attacked by boiling water. Trivalent actinide ions behave similarly to the trivalent lanthanide ions hence the sulfides in question may be insoluble but this is not explicitly stated. Tervalent An sulfides decompose but Edelstein et al. say they are soluble whereas Haynes says thorium(IV) sulfide is insoluble. Early in the history of nuclear fission it had been noted that precipitation with hydrogen sulfide was a "remarkably" effective way of isolating and detecting transuranium elements in solution. In a similar vein, Deschlag writes that the elements after uranium were expected to have insoluble sulfides by analogy with third row transition metals. But he goes on to note that the elements after actinium were found to have properties different from those of the transition metals and claims they do not form insoluble sulfides. The An hydroxides are, however, insoluble and can be precipitated from aqueous solutions of their salts. Finally, many An complexes have "deep and vivid" colours.
- The heavier elements commonly to less commonly recognised as metalloids—Ge; As, Sb; Se, Te, Po; At—satisfy some of the three parts of Hawkes' definition. All of them have insoluble sulfides but only Ge, Te, and Po apparently have effectively insoluble hydroxides. All bar At can be obtained as coloured (sulfide) precipitates from aqueous solutions of their salts; astatine is likewise precipitated from solution by hydrogen sulfide but, since visible quantities of At have never been synthesised, the colour of the precipitate is not known. As p-block elements, their complexes are usually colourless.
- The class A and class B terminology is analogous to the "hard acid" and "soft base" terminology sometimes used to refer to the behaviour of metal ions in inorganic systems.
- Be and Al are exceptions to this general trend. They have somewhat higher electronegativity values. Being relatively small their +2 or +3 ions have high charge densities, thereby polarising nearby electron clouds. The net result is that Be and Al compounds have considerable covalent character.
- Google Scholar has recorded more than 1200 citations for the paper in question.
- If Gmelin had been working with the imperial system of weights and measures he may have chosen 300 lb/ft3 as his light/heavy metal cutoff in which case selenium (density 300.27 lb/ft3 ) would have made the grade, whereas 5 g/cm3 = 312.14lb/ft3.
- Lead, which is a cumulative poison, has a relatively high abundance due to its extensive historical use and human-caused discharge into the environment.
- Haynes shows an amount of < 17 mg for tin
- Iyengar records a figure of 5 mg for nickel; Haynes shows an amount of 10 mg
- Encompassing 45 heavy metals occurring in quantities of less than 10 mg each, including As (7 mg), Mo (5), Co (1.5), and Cr (1.4)
- Of the elements commonly recognised as metalloids, B and Si were counted as nonmetals; Ge, As, Sb, and Te as heavy metals.
- Ni, Cu, Zn, Se, Ag and Sb appear in the United States Government's Toxic Pollutant List; Mn, Co, and Sn are listed in the Australian Government's National Pollutant Inventory.
- Tungsten could be another such toxic heavy metal.
- Selenium is the most toxic of the heavy metals that are essential for mammals.
- Trace elements having an abundance equalling or much less than one part per trillion (namely Tc, Pm, Po, At, Ra, Ac, Pa, Np, and Pu) are not shown. Abundances are from Lide and Emsley; occurrence types are from McQueen.
- In some cases, for example in the presence of high energy gamma rays or in a very high temperature hydrogen rich environment, the subject nuclei may experience neutron loss or proton gain resulting in the production of (comparatively rare) neutron deficient isotopes.
- The ejection of matter when two neutron stars collide is attributed to the interaction of their tidal forces, possible crustal disruption, and shock heating (which is what happens if you floor the accelerator in car when the engine is cold).
- Iron, cobalt, nickel, germanium and tin are also siderophiles from a whole of Earth perspective.
- Heat escaping from the inner solid core is believed to generate motion in the outer core, which is made of liquid iron alloys. The motion of this liquid generates electrical currents which give rise to a magnetic field.
- Heavy metals that occur naturally in quantities too small to be economically mined (Tc, Pm, Po, At, Ac, Np and Pu) are instead produced by artificial transmutation. The latter method is also used to produce heavy metals from americium onwards.
- Sulfides of the Group 1 and 2 metals, and aluminium, are hydrolysed by water; scandium, yttrium and titanium sulfides are insoluble.
- For example, the hydroxides of potassium, rubidium, and caesium have solubilities exceeding 100 grams per 100 grams of water whereas those of aluminium (0.0001) and scandium (<0.000 000 15 grams) are regarded as being insoluble.
- Beryllium has what is described as a "high" melting point of 1560 K; scandium and titanium melt at 1814 and 1941 K.
- Zinc is a soft metal with a Moh's hardness of 2.5; cadmium and lead have lower hardness ratings of 2.0 and 1.5. Zinc has a "low" melting point of 693 K; cadmium and lead melt at 595 and 601 K.
- Some violence and abstraction of detail was applied to the sorting scheme in order to keep the number of categories to a manageable level.
- The skin has largely turned green due to the formation of a protective patina composed of antlerite Cu3(OH)4SO4, atacamite Cu4(OH)6Cl2, brochantite Cu4(OH)6SO4, cuprous oxide Cu2O, and tenorite CuO.
- For the lanthanides, this is their only structural use as they are otherwise too reactive, relatively expensive, and moderately strong at best.
- Weller classifies coinage metals as precious metals (e.g., silver, gold, platinum); heavy metals of very high durability (nickel); heavy metals of low durability (copper, iron, zinc, tin, and lead); and light metals (aluminium).
- Emsley estimates a global loss of six tonnes of gold a year due to 18-carat wedding rings slowly wearing away.
- Sheet lead exposed to the rigours of industrial and coastal climates will last for centuries
- Electrons impacting the tungsten anode generate X-rays; rhenium gives tungsten better resistance to thermal shock; molybdenum and graphite act as heat sinks. Molybdenum also has a density nearly half that of tungsten thereby reducing the weight of the anode.
- Emsley 2011, pp. 288; 374
- Pourret, Olivier (August 2018). "On the Necessity of Banning the Term "Heavy Metal" from the Scientific Literature" (PDF). Sustainability. 10 (8): 2879. doi:10.3390/su10082879.
- Duffus 2002, p. 798
- Rand, Wells & McCarty 1995, p. 23
- Baldwin & Marshall 1999, p. 267
- Lyman 2003, p. 452
- The United States Pharmacopeia 1985, p. 1189
- Raghuram, Soma Raju & Sriramulu 2010, p. 15
- Thorne & Roberts 1943, p. 534
- Hawkes 1997
- Nieboer & Richardson 1980, p. 4
- Emsley 2011
- Hoffman, Lee & Pershina 2011, pp. 1691,1723; Bonchev & Kamenska 1981, p. 1182
- Silva 2010, pp. 1628, 1635, 1639, 1644
- Fournier 1976, p. 243
- Vernon 2013, p. 1703
- Morris 1992, p. 1001
- Gorbachev, Zamyatnin & Lbov 1980, p. 5
- Duffus 2002, p. 797
- Liens 2010, p. 1415
- Longo 1974, p. 683
- Tomasik & Ratajewicz 1985, p. 433
- Herron 2000, p. 511
- Nathans 1963, p. 265
- Topp 1965, p. 106: Schweitzer & Pesterfield 2010, p. 284
- King 1995, p. 297; Mellor 1924, p. 628
- Cotton 2006, pp. 66
- Albutt & Dell 1963, p. 1796
- Wiberg 2001, pp. 1722–1723
- Wiberg 2001, p. 1724
- Edelstein et al. 2010, p. 1796
- Haynes 2015, pp. 4–95
- Weart 1983, p. 94
- Deschlag 2011, p. 226
- Wulfsberg 2000, pp. 209–211
- Ahrland, Liljenzin & Rydberg 1973, p. 478
- Korenman 1959, p. 1368
- Yang, Jolly & O'Keefe 1977, p. 2980; Wiberg 2001, pp. 592; Kolthoff & Elving 1964, p. 529
- Close 2015, p. 78
- Parish 1977, p. 89
- Rainbow 1991, p. 416
- Nieboer & Richardson 1980, pp. 6–7
- Lee 1996, pp. 332; 364
- Clugston & Flemming 2000, pp. 294; 334, 336
- Nieboer & Richardson 1980, p. 7
- Nieboer & Richardson 1980
- Hübner, Astin & Herbert 2010, pp. 1511–1512
- Järup & 2003, p. 168; Rasic-Milutinovic & Jovanovic 2013, p. 6; Wijayawardena, Megharaj & Naidu 2016, p. 176
- Duffus 2002, pp. 794–795; 800
- Emsley 2011, p. 480
- USEPA 1988, p. 1; Uden 2005, pp. 347–348; DeZuane 1997, p. 93; Dev 2008, pp. 2–3
- Ikehata et al. 2015, p. 143
- Emsley 2011, p. 71
- Emsley 2011, p. 30
- Podsiki 2008, p. 1
- Emsley 2011, p. 106
- Emsley 2011, p. 62
- Chakhmouradian, Smith & Kynicky 2015, pp. 456–457
- Cotton 1997, p. ix; Ryan 2012, p. 369
- Hermann, Hoffmann & Ashcroft 2013, p. 11604-1
- Emsley 2011, p. 75
- Gribbon 2016, p. x
- Emsley 2011, pp. 428–429; 414; Wiberg 2001, pp. 527; Emsley 2011, pp. 437; 21–22; 346–347; 408–409
- Raymond 1984, pp. 8–9
- Chambers 1743: "That which distinguishes metals from all other bodies ... is their heaviness ..."
- Oxford English Dictionary 1989; Gordh & Headrick 2003, p. 753
- Goldsmith 1982, p. 526
- Habashi 2009, p. 31
- Gmelin 1849, p. 2
- Magee 1969, p. 14
- Ridpath 2012, p. 208
- Duffus 2002, p. 794
- Leeper 1978, p. ix
- Housecroft 2008, p. 802
- Shaw, Sahu & Mishra 1999, p. 89; Martin & Coughtrey 1982, pp. 2–3
- Hübner, Astin & Herbert 2010, p. 1513
- The Minerals, Metals and Materials Society 2016
- Emsley 2011, pp. 35; passim
- Emsley 2011, pp. 280, 286; Baird & Cann 2012, pp. 549, 551
- Haynes 2015, pp. 7–48
- Iyengar 1998, p. 553
- Emsley 2011, pp. 47; 331; 138; 133; passim
- Nieboer & Richardson 1978, p. 2
- Emsley 2011, pp. 604; 31; 133; 358; 47; 475
- Valkovic 1990, pp. 214, 218
- Emsley 2011, pp. 331; 89; 552
- Emsley 2011, p. 571
- Venugopal & Luckey 1978, p. 307
- Emsley 2011, pp. 24; passim
- Emsley 2011, pp. 192; 197; 240; 120, 166, 188, 224, 269, 299, 423, 464, 549, 614; 559
- Duffus 2002, pp. 794; 799
- Baird & Cann 2012, p. 519
- Kozin & Hansen 2013, p. 80
- Baird & Cann 2012, pp. 519–520; 567; Rusyniak et al. 2010, p. 387
- Di Maio 2001, p. 208
- Perry & Vanderklein 1996, p. 208
- Love 1998, p. 208
- Hendrickson 2016, p. 42
- Reyes 2007, pp. 1, 20, 35–36
- Emsley 2011, p. 311
- Wiberg 2001, pp. 1474, 1501
- Tokar et al. 2013
- Eisler 1993, pp. 3, passim
- Lemly 1997, p. 259; Ohlendorf 2003, p. 490
- State Water Control Resources Board 1987, p. 63
- Scott 1989, pp. 107–108
- International Antimony Association 2016
- United States Government 2014
- Australian Government 2016
- United States Environmental Protection Agency 2014
- Ong, Tan & Cheung 1997, p. 44
- Emsley 2011, p. 146
- Emsley 2011, p. 476
- Selinger 1978, p. 369
- Cole & Stuart 2000, p. 315
- Clegg 2014
- Emsley 2011, p. 240
- Emsley 2011, p. 595
- Stankovic & Stankovic 2013, pp. 154–159
- Bradl 2005, pp. 15, 17–20
- Harvey, Handley & Taylor 2015, p. 12276
- Howell et al. 2012; Cole et al. 2011, pp. 2589–2590
- Amasawa et al. 2016, pp. 95–101
- Massarani 2015
- Torrice 2016
- Lide 2004, pp. 14–17
- Emsley 2011, pp. 29; passim
- McQueen 2009, p. 74
- Cox 1997, pp. 73–89
- Cox 1997, pp. 32, 63, 85
- Podosek 2011, p. 482
- Padmanabhan 2001, p. 234
- Rehder 2010, pp. 32, 33
- Hofmann 2002, pp. 23–24
- Hadhazy 2016
- Choptuik, Lehner & Pretorias 2015, p. 383
- Cox 1997, pp. 83, 91, 102–103
- Berry & Mason 1959, pp. 210–211; Rankin 2011, p. 69
- Hartmann 2005, p. 197
- Yousif 2007, pp. 11–12
- Berry & Mason 1959, pp. 214
- Yousif 2007, pp. 11
- Wiberg 2001, p. 1511
- Emsley 2011, p. 403
- Litasov & Shatskiy 2016, p. 27
- Sanders 2003; Preuss 2011
- Natural Resources Canada 2015
- MacKay, MacKay & Henderson 2002, pp. 203–204
- Emsley 2011, pp. 525–528; 428–429; 414; 57–58; 22; 346–347; 408–409; Keller, Wolf & Shani 2012, p. 98
- Emsley 2011, pp. 32 et seq.
- Emsley 2011, pp. 437
- Chen & Huang 2006, p. 208; Crundwell et al. 2011, pp. 411–413; Renner et al. 2012, p. 332; Seymour & O'Farrelly 2012, pp. 10–12
- Crundwell et al. 2011, p. 409
- International Platinum Group Metals Association n.d., pp. 3–4
- McLemore 2008, p. 44
- Wiberg 2001, p. 1277
- Russell & Lee 2005, p. 437
- McCurdy 1992, p. 186
- von Zeerleder 1949, p. 68
- Chawla & Chawla 2013, p. 55
- von Gleich 2006, p. 3
- Biddle & Bush 1949, p. 180
- Magill 1992, p. 1380
- Gidding 1973, pp. 335–336
- Wiberg 2001, p. 520
- Schweitzer & Pesterfield 2010, p. 230
- Macintyre 1994, p. 334
- Booth 1957, p. 85; Haynes 2015, pp. 4–96
- Schweitzer & Pesterfield 2010, p. 230. The authors note, however, that, "The sulfides of ... Ga(III) and Cr(III) tend to dissolve and/or decompose in water."
- Sidgwick 1950, p. 96
- Ondreička, Kortus & Ginter 1971, p. 294
- Gschneidner 1975, p. 195
- Hasan 1996, p. 251
- Brady & Holum 1995, p. 825
- Cotton 2006, pp. 66; Ahrland, Liljenzin & Rydberg 1973, p. 478
- Nieboer & Richardson 1980, p. 10
- Russell & Lee 2005, pp. 158, 434, 180
- Schweitzer 2003, p. 603
- Samsonov 1968, p. 432
- Russell & Lee 2005, pp. 338–339; 338; 411
- Emsley 2011, pp. 260; 401
- Jones 2001, p. 3
- Berea, Rodriguez-lbelo & Navarro 2016, p. 203
- Alves, Berutti & Sánchez 2012, p. 94
- Yadav, Antony & Subba Reddy 2012, p. 231
- Masters 1981, p. 5
- Wulfsberg 1987, pp. 200–201
- Bryson & Hammond 2005, p. 120 (high electron density); Frommer & Stabulas-Savage 2014, pp. 69–70 (high atomic number)
- Landis, Sofield & Yu 2011, p. 269
- Prieto 2011, p. 10; Pickering 1991, pp. 5–6, 17
- Emsley 2011, p. 286
- Berger & Bruning 1979, p. 173
- Jackson & Summitt 2006, pp. 10, 13
- Shedd 2002, p. 80.5; Kantra 2001, p. 10
- Spolek 2007, p. 239
- White 2010, p. 139
- Dapena & Teves 1982, p. 78
- Burkett 2010, p. 80
- Moore & Ramamoorthy 1984, p. 102
- National Materials Advisory Board 1973, p. 58
- Livesey 2012, p. 57
- VanGelder 2014, pp. 354, 801
- National Materials Advisory Board 1971, pp. 35–37
- Frick 2000, p. 342
- Rockhoff 2012, p. 314
- Russell & Lee 2005, pp. 16, 96
- Morstein 2005, p. 129
- Russell & Lee 2005, pp. 218–219
- Lach et al. 2015; Di Maio 2016, p. 154
- Preschel 2005; Guandalini et al. 2011, p. 488
- Scoullos et al. 2001, p. 315; Ariel, Barta & Brandon 1973, p. 126
- Wingerson 1986, p. 35
- Matyi & Baboian 1986, p. 299; Livingston 1991, pp. 1401, 1407
- Casey 1993, p. 156
- Bradl 2005, p. 25
- Kumar, Srivastava & Srivastava 1994, p. 259
- Nzierżanowski & Gawroński 2012, p. 42
- Pacheco-Torgal, Jalali & Fucic 2012, pp. 283–294; 297–333
- Venner et al. 2004, p. 124
- Technical Publications 1958, p. 235: "Here is a rugged hard metal cutter ... for cutting ... through ... padlocks, steel grilles and other heavy metals."
- Naja & Volesky 2009, p. 41
- Department of the Navy 2009, pp. 3.3–13
- Rebhandl et al. 2007, p. 1729
- Greenberg & Patterson 2008, p. 239
- Russell & Lee 2005, pp. 437, 441
- Roe & Roe 1992
- Weller 1976, p. 4
- Emsley 2011, p. 208
- Emsley 2011, p. 206
- Guney & Zagury 2012, p. 1238; Cui et al. 2015, p. 77
- Brephol & McCreight 2001, p. 15
- Russell & Lee 2005, pp. 337, 404, 411
- Emsley 2011, pp. 141; 286
- Emsley 2011, pp. 625
- Emsley 2011, pp. 555, 557
- Emsley 2011, p. 531
- Emsley 2011, p. 123
- Weber & Rutula 2001, p. 415
- Dunn 2009; Bonetti et al. 2009, pp. 1, 84, 201
- Desoize 2004, p. 1529
- Atlas 1986, p. 359; Lima et al. 2013, p. 1
- Volesky 1990, p. 174
- Nakbanpote, Meesungnoen & Prasad 2016, p. 180
- Emsley 2011, pp. 447; 74; 384; 123
- Elliot 1946, p. 11; Warth 1956, p. 571
- McColm 1994, p. 215
- Emsley 2011, pp. 135; 313; 141; 495; 626; 479; 630; 334; 495; 556; 424; 339; 169; 571; 252; 205; 286; 599
- Everts 2016
- Emsley 2011, p. 450
- Emsley 2011, p. 334
- Emsley 2011, p. 459
- Moselle 2004, pp. 409–410
- Russell & Lee 2005, p. 323
- Emsley 2011, p. 212
- Tretkoff 2006
- Emsley 2011, pp. 428; 276; 326–327
- Emsley 2011, pp. 73; 141; 141; 141; 355; 73; 424; 340; 189; 189
- Emsley 2011, pp. 192; 242; 194
- Baranoff 2015, p. 80; Wong et al. 2015, p. 6535
- Ball, Moore & Turner 2008, p. 177
- Ball, Moore & Turner 2008, pp. 248–249, 255
- Russell & Lee 2005, p. 238
- Tisza 2001, p. 73
- Chandler & Roberson 2009, pp. 47, 367–369, 373; Ismail, Khulbe & Matsuura 2015, p. 302
- Ebbing & Gammon 2017, p. 695
- Pan & Dai 2015, p. 69
- Brown 1987, p. 48
- Ahrland S., Liljenzin J. O. & Rydberg J. 1973, "Solution chemistry," in J. C. Bailar & A. F. Trotman-Dickenson (eds), Comprehensive Inorganic Chemistry, vol. 5, The Actinides, Pergamon Press, Oxford.
- Albutt M. & Dell R. 1963, The nitrites and sulphides of uranium, thorium and plutonium: A review of present knowledge, UK Atomic Energy Authority Research Group, Harwell, Berkshire.
- Alves A. K., Berutti, F. A. & Sánche, F. A. L. 2012, "Nanomaterials and catalysis", in C. P. Bergmann & M. J. de Andrade (ads), Nanonstructured Materials for Engineering Applications, Springer-Verlag, Berlin, ISBN 978-3-642-19130-5.
- Amasawa E., Yi Teah H., Yu Ting Khew, J., Ikeda I. & Onuki M. 2016, "Drawing Lessons from the Minamata Incident for the General Public: Exercise on Resilience, Minamata Unit AY2014", in M. Esteban, T. Akiyama, C. Chen, I. Ikea, T. Mino (eds), Sustainability Science: Field Methods and Exercises, Springer International, Switzerland, pp. 93–116, doi:10.1007/978-3-319-32930-7_5 ISBN 978-3-319-32929-1.
- Ariel E., Barta J. & Brandon D. 1973, "Preparation and properties of heavy metals", Powder Metallurgy International, vol. 5, no. 3, pp. 126–129.
- Atlas R. M. 1986, Basic and Practical Microbiology, Macmillan Publishing Company, New York, ISBN 978-0-02-304350-5.
- Australian Government 2016, National Pollutant Inventory, Department of the Environment and Energy, accessed 16 August 2016.
- Baird C. & Cann M. 2012, Environmental Chemistry, 5th ed., W. H. Freeman and Company, New York, ISBN 978-1-4292-7704-4.
- Baldwin D. R. & Marshall W. J. 1999, "Heavy metal poisoning and its laboratory investigation", Annals of Clinical Biochemistry, vol. 36, no. 3, pp. 267–300, doi:10.1177/000456329903600301.
- Ball J. L., Moore A. D. & Turner S. 2008, Ball and Moore's Essential Physics for Radiographers, 4th ed., Blackwell Publishing, Chichester, ISBN 978-1-4051-6101-5.
- Bánfalvi G. 2011, "Heavy metals, trace elements and their cellular effects", in G. Bánfalvi (ed.), Cellular Effects of Heavy Metals, Springer, Dordrecht, pp. 3–28, ISBN 978-94-007-0427-5.
- Baranoff E. 2015, "First-row transition metal complexes for the conversion of light into electricity and electricity into light", in W-Y Wong (ed.), Organometallics and Related Molecules for Energy Conversion, Springer, Heidelberg, pp. 61–90, ISBN 978-3-662-46053-5.
- Berea E., Rodriguez-lbelo M. & Navarro J. A. R. 2016, "Platinum Group Metal—Organic frameworks" in S. Kaskel (ed.), The Chemistry of Metal-Organic Frameworks: Synthesis, Characterisation, and Applications, vol. 2, Wiley-VCH Weinheim, pp. 203–230, ISBN 978-3-527-33874-0.
- Berger A. J. & Bruning N. 1979, Lady Luck's Companion: How to Play ... How to Enjoy ... How to Bet ... How to Win, Harper & Row, New York, ISBN 978-0-06-014696-2.
- Berry L. G. & Mason B. 1959, Mineralogy: Concepts, Descriptions, Determinations, W. H. Freeman and Company, San Francisco.
- Biddle H. C. & Bush G. L 1949, Chemistry Today, Rand McNally, Chicago.
- Bonchev D. & Kamenska V. 1981, "Predicting the properties of the 113–120 transactinide elements", The Journal of Physical Chemistry, vo. 85, no. 9, pp. 1177–1186, doi:10.1021/j150609a021.
- Bonetti A., Leone R., Muggia F. & Howell S. B. (eds) 2009, Platinum and Other Heavy Metal Compounds in Cancer Chemotherapy: Molecular Mechanisms and Clinical Applications, Humana Press, New York, ISBN 978-1-60327-458-6.
- Booth H. S. 1957, Inorganic Syntheses, vol. 5, McGraw-Hill, New York.
- Bradl H. E. 2005, "Sources and origins of heavy metals", in Bradl H. E. (ed.), Heavy Metals in the Environment: Origin, Interaction and Remediation, Elsevier, Amsterdam, ISBN 978-0-12-088381-3.
- Brady J. E. & Holum J. R. 1995, Chemistry: The Study of Matter and its Changes, 2nd ed., John Wiley & Sons, New York, ISBN 978-0-471-10042-3.
- Brephohl E. & McCreight T. (ed) 2001, The Theory and Practice of Goldsmithing, C. Lewton-Brain trans., Brynmorgen Press, Portland, Maine, ISBN 978-0-9615984-9-5.
- Brown I. 1987, "Astatine: Its organonuclear chemistry and biomedical applications," in H. J. Emeléus & A. G. Sharpe (eds), Advances in Inorganic Chemistry, vol. 31, Academic Press, Orlando, pp. 43–88, ISBN 978-0-12-023631-2.
- Bryson R. M. & Hammond C. 2005, "Generic methodologies for nanotechnology: Characterisation"', in R. Kelsall, I. W. Hamley & M. Geoghegan, Nanoscale Science and Technology, John Wiley & Sons, Chichester, pp. 56–129, ISBN 978-0-470-85086-2.
- Burkett B. 2010, Sport Mechanics for Coaches, 3rd ed., Human Kinetics, Champaign, Illinois, ISBN 978-0-7360-8359-1.
- Casey C. 1993, "Restructuring work: New work and new workers in post-industrial production", in R. P. Coulter & I. F. Goodson (eds), Rethinking Vocationalism: Whose Work/life is it?, Our Schools/Our Selves Education Foundation, Toronto, ISBN 978-0-921908-15-9.
- Chakhmouradian A.R., Smith M. P. & Kynicky J. 2015, "From "strategic" tungsten to "green" neodymium: A century of critical metals at a glance", Ore Geology Reviews, vol. 64, January, pp. 455–458, doi:10.1016/j.oregeorev.2014.06.008.
- Chambers E. 1743, "Metal", in Cyclopedia: Or an Universal Dictionary of Arts and Sciences (etc.), vol. 2, D. Midwinter, London.
- Chandler D. E. & Roberson R. W. 2009, Bioimaging: Current Concepts in Light & Electron Microscopy, Jones & Bartlett Publishers, Boston, ISBN 978-0-7637-3874-7.
- Chawla N. & Chawla K. K. 2013, Metal matrix composites, 2nd ed., Springer Science+Business Media, New York, ISBN 978-1-4614-9547-5.
- Chen J. & Huang K. 2006, "A new technique for extraction of platinum group metals by pressure cyanidation", Hydrometallurgy, vol. 82, nos. 3–4, pp. 164–171, doi:10.1016/j.hydromet.2006.03.041.
- Choptuik M. W., Lehner L. & Pretorias F. 2015, "Probing strong-field gravity through numerical simulation", in A. Ashtekar, B. K. Berger, J. Isenberg & M. MacCallum (eds), General Relativity and Gravitation: A Centennial Perspective, Cambridge University Press, Cambridge, ISBN 978-1-107-03731-1.
- Clegg B 2014, "Osmium tetroxide", Chemistry World, accessed 2 September 2016.
- Close F. 2015, Nuclear Physics: A Very Short Introduction, Oxford University Press, Oxford, ISBN 978-0-19-871863-5.
- Clugston M & Flemming R 2000, Advanced Chemistry, Oxford University, Oxford, ISBN 978-0-19-914633-8.
- Cole M., Lindeque P., Halsband C. & Galloway T. S. 2011, "Microplastics as contaminants in the marine environment: A review", Marine Pollution Bulletin, vol. 62, no. 12, pp. 2588–2597, doi:10.1016/j.marpolbul.2011.09.025.
- Cole S. E. & Stuart K. R. 2000, "Nuclear and cortical histology for brightfield microscopy", in D. J. Asai & J. D. Forney (eds), Methods in Cell Biology, vol. 62, Academic Press, San Diego, pp. 313–322, ISBN 978-0-12-544164-3.
- Cotton S. A. 1997, Chemistry of Precious Metals, Blackie Academic & Professional, London, ISBN 978-94-010-7154-3.
- Cotton S. 2006, Lanthanide and Actinide Chemistry, reprinted with corrections 2007, John Wiley & Sons, Chichester, ISBN 978-0-470-01005-1.
- Cox P. A. 1997, The elements: Their Origin, Abundance and Distribution, Oxford University Press, Oxford, ISBN 978-0-19-855298-7.
- Crundwell F. K., Moats M. S., Ramachandran V., Robinson T. G. & Davenport W. G. 2011, Extractive Metallurgy of Nickel, Cobalt and Platinum Group Metals, Elsevier, Kidlington, Oxford, ISBN 978-0-08-096809-4.
- Cui X-Y., Li S-W., Zhang S-J., Fan Y-Y., Ma L. Q. 2015, "Toxic metals in children's toys and jewelry: Coupling bioaccessibility with risk assessment", Environmental Pollution, vol. 200, pp. 77–84, doi:10.1016/j.envpol.2015.01.035.
- Dapena J. & Teves M. A. 1982, "Influence of the diameter of the hammer head on the distance of a hammer throw", Research Quarterly for Exercise and Sport, vol. 53, no. 1, pp. 78–81, doi:10.1080/02701367.1982.10605229.
- De Zuane J. 1997, Handbook of Drinking Water Quality, 2nd ed., John Wiley & Sons, New York, ISBN 978-0-471-28789-6.
- Department of the Navy 2009, Gulf of Alaska Navy Training Activities: Draft Environmental Impact Statement/Overseas Environmental Impact Statement, U.S. Government, accessed 21 August 2016.
- Deschlag J. O. 2011, "Nuclear fission", in A. Vértes, S. Nagy, Z. Klencsár, R. G. Lovas, F. Rösch (eds), Handbook of Nuclear Chemistry, 2nd ed., Springer Science+Business Media, Dordrecht, pp. 223–280, ISBN 978-1-4419-0719-6.
- Desoize B. 2004, "Metals and metal compounds in cancer treatment", Anticancer Research, vol. 24, no. 3a, pp. 1529–1544, PMID 15274320.
- Dev N. 2008, 'Modelling Selenium Fate and Transport in Great Salt Lake Wetlands', PhD dissertation, University of Utah, ProQuest, Ann Arbor, Michigan, ISBN 978-0-549-86542-1.
- Di Maio V. J. M. 2001, Forensic Pathology, 2nd ed., CRC Press, Boca Raton, ISBN 0-8493-0072-X.
- Di Maio V. J. M. 2016, Gunshot Wounds: Practical Aspects of Firearms, Ballistics, and Forensic Techniques, 3rd ed., CRC Press, Boca Raton, Florida, ISBN 978-1-4987-2570-5.
- Duffus J. H. 2002, " 'Heavy metals'—A meaningless term?", Pure and Applied Chemistry, vol. 74, no. 5, pp. 793–807, doi:10.1351/pac200274050793.
- Dunn P. 2009, Unusual metals could forge new cancer drugs, University of Warwick, accessed 23 March 2016.
- Ebbing D. D. & Gammon S. D. 2017, General Chemistry, 11th ed., Cengage Learning, Boston, ISBN 978-1-305-58034-3.
- Edelstein N. M., Fuger J., Katz J. L. & Morss L. R. 2010, "Summary and comparison of properties of the actinde and transactinide elements," in L. R. Morss, N. M. Edelstein & J. Fuger (eds), The Chemistry of the Actinide and Transactinide Elements, 4th ed., vol. 1–6, Springer, Dordrecht, pp. 1753–1835, ISBN 978-94-007-0210-3.
- Eisler R. 1993, Zinc Hazards to Fish, Wildlife, and Invertebrates: A Synoptic Review, Biological Report 10, U. S. Department of the Interior, Laurel, Maryland, accessed 2 September 2016.
- Elliott S. B. 1946, The Alkaline-earth and Heavy-metal Soaps, Reinhold Publishing Corporation, New York.
- Emsley J. 2011, Nature's Building Blocks, new edition, Oxford University Press, Oxford, ISBN 978-0-19-960563-7.
- Everts S. 2016, "What chemicals are in your tattoo", Chemical & Engineering News, vol. 94, no. 33, pp. 24–26.
- Fournier J. 1976, "Bonding and the electronic structure of the actinide metals," Journal of Physics and Chemistry of Solids, vol 37, no. 2, pp. 235–244, doi:10.1016/0022-3697(76)90167-0.
- Frick J. P. (ed.) 2000, Woldman's Engineering Alloys, 9th ed., ASM International, Materials Park, Ohio, ISBN 978-0-87170-691-1.
- Frommer H. H. & Stabulas-Savage J. J. 2014, Radiology for the Dental Professional, 9th ed., Mosby Inc., St. Louis, Missouri, ISBN 978-0-323-06401-9.
- Gidding J. C. 1973, Chemistry, Man, and Environmental Change: An Integrated Approach, Canfield Press, New York, ISBN 978-0-06-382790-5.
- Gmelin L. 1849, Hand-book of chemistry, vol. III, Metals, translated from the German by H. Watts, Cavendish Society, London.
- Goldsmith R. H. 1982, "Metalloids", Journal of Chemical Education, vol. 59, no. 6, pp. 526–527, doi:10.1021/ed059p526.
- Gorbachev V. M., Zamyatnin Y. S. & Lbov A. A. 1980, Nuclear Reactions in Heavy Elements: A Data Handbook, Pergamon Press, Oxford, ISBN 978-0-08-023595-0.
- Gordh G. & Headrick D. 2003, A Dictionary of Entomology, CABI Publishing, Wallingford, ISBN 978-0-85199-655-4.
- Greenberg B. R. & Patterson D. 2008, Art in Chemistry; Chemistry in Art, 2nd ed., Teachers Ideas Press, Westport, Connecticut, ISBN 978-1-59158-309-7.
- Gribbon J. 2016, 13.8: The Quest to Find the True Age of the Universe and the Theory of Everything, Yale University Press, New Haven, ISBN 978-0-300-21827-5.
- Gschneidner Jr., K. A. 1975, Inorganic compounds, in C. T. Horowitz (ed.), Scandium: Its Occurrence, Chemistry, Physics, Metallurgy, Biology and Technology, Academic Press, London, pp. 152–251, ISBN 978-0-12-355850-3.
- Guandalini G. S., Zhang L., Fornero E., Centeno J. A., Mokashi V. P., Ortiz P. A., Stockelman M. D., Osterburg A. R. & Chapman G. G. 2011, "Tissue distribution of tungsten in mice following oral exposure to sodium tungstate," Chemical Research in Toxicology, vol. 24, no. 4, pp 488–493, doi:10.1021/tx200011k.
- Guney M. & Zagury G. J. 2012, "Heavy metals in toys and low-cost jewelry: Critical review of U.S. and Canadian legislations and recommendations for testing", Environmental Science & Technology, vol. 48, pp. 1238–1246, doi:10.1021/es4036122.
- Habashi F. 2009, "Gmelin and his Handbuch", Bulletin for the History of Chemistry, vol. 34, no. 1, pp. 30–1.
- Hadhazy A. 2016, "Galactic 'gold mine' explains the origin of nature's heaviest elements", Science Spotlights, 10 May 2016, accessed 11 July 2016.
- Hartmann W. K. 2005, Moons & Planets, 5th ed., Thomson Brooks/Cole, Belmont, California, ISBN 978-0-534-49393-6.
- Harvey P. J., Handley H. K. & Taylor M. P. 2015, "Identification of the sources of metal (lead) contamination in drinking waters in north-eastern Tasmania using lead isotopic compositions," Environmental Science and Pollution Research, vol. 22, no. 16, pp. 12276–12288, doi:10.1007/s11356-015-4349-2 PMID 25895456.
- Hasan S. E. 1996, Geology and Hazardous Waste Management, Prentice Hall, Upper Saddle River, New Jersey, ISBN 978-0-02-351682-5.
- Hawkes S. J. 1997, "What is a "heavy metal"?", Journal of Chemical Education, vol. 74, no. 11, p. 1374, doi:10.1021/ed074p1374.
- Haynes W. M. 2015, CRC Handbook of Chemistry and Physics, 96th ed., CRC Press, Boca Raton, Florida, ISBN 978-1-4822-6097-7.
- Hendrickson D. J. 2916, "Effects of early experience on brain and body", in D. Alicata, N. N. Jacobs, A. Guerrero and M. Piasecki (eds), Problem-based Behavioural Science and Psychiatry 2nd ed., Springer, Cham, pp. 33–54, ISBN 978-3-319-23669-8.
- Hermann A., Hoffmann R. & Ashcroft N. W. 2013, "Condensed astatine: Monatomic and metallic", Physical Review Letters, vol. 111, pp. 11604–1−11604-5, doi:10.1103/PhysRevLett.111.116404.
- Herron N. 2000, "Cadmium compounds," in Kirk-Othmer Encyclopedia of Chemical Technology, vol. 4, John Wiley & Sons, New York, pp. 507–523, ISBN 978-0-471-23896-6.
- Hoffman D. C., Lee D. M. & Pershina V. 2011, "Transactinide elements and future elements," in L. R. Morss, N. Edelstein, J. Fuger & J. J. Katz (eds), The Chemistry of the Actinide and Transactinide Elements, 4th ed., vol. 3, Springer, Dordrecht, pp. 1652–1752, ISBN 978-94-007-0210-3.
- Hofmann S. 2002, On Beyond Uranium: Journey to the End of the Periodic Table, Taylor & Francis, London, ISBN 978-0-415-28495-0.
- Housecroft J. E. 2008, Inorganic Chemistry, Elsevier, Burlington, Massachusetts, ISBN 978-0-12-356786-4.
- Howell N., Lavers J., Paterson D., Garrett R. & Banati R. 2012, Trace metal distribution in feathers from migratory, pelagic birds, Australian Nuclear Science and Technology Organisation, accessed 3 May 2014.
- Hübner R., Astin K. B. & Herbert R. J. H. 2010, " 'Heavy metal'—time to move on from semantics to pragmatics?", Journal of Environmental Monitoring, vol. 12, pp. 1511–1514, doi:10.1039/C0EM00056F.
- Ikehata K., Jin Y., Maleky N. & Lin A. 2015, "Heavy metal pollution in water resources in China—Occurrence and public health implications", in S. K. Sharma (ed.), Heavy Metals in Water: Presence, Removal and Safety, Royal Society of Chemistry, Cambridge, pp. 141–167, ISBN 978-1-84973-885-9.
- International Antimony Association 2016, Antimony compounds, accessed 2 September 2016.
- International Platinum Group Metals Association n.d., The Primary Production of Platinum Group Metals (PGMs), accessed 4 September 2016.
- Ismail A. F., Khulbe K. & Matsuura T. 2015, Gas Separation Membranes: Polymeric and Inorganic, Springer, Cham, Switzerland, ISBN 978-3-319-01095-3.
- IUPAC 2016, "IUPAC is naming the four new elements nihonium, moscovium, tennessine, and oganesson" accessed 27 August 2016.
- Iyengar G. V. 1998, "Reevaluation of the trace element content in Reference Man", Radiation Physics and Chemistry, vol. 51, nos 4–6, pp. 545–560, doi:10.1016/S0969-806X(97)00202-8
- Jackson J. & Summitt J. 2006, The Modern Guide to Golf Clubmaking: The Principles and Techniques of Component Golf Club Assembly and Alteration, 5th ed., Hireko Trading Company, City of Industry, California, ISBN 978-0-9619413-0-7.
- Järup L 2003, "Hazards of heavy metal contamination", British Medical Bulletin, vol. 68, no. 1, pp. 167–182, doi:10.1093/bmb/ldg032.
- Jones C. J. 2001, d- and f-Block Chemistry, Royal Society of Chemistry, Cambridge, ISBN 978-0-85404-637-9.
- Kantra S. 2001, "What's new", Popular Science, vol. 254, no. 4, April, p. 10.
- Keller C., Wolf W. & Shani J. 2012, "Radionuclides, 2. Radioactive elements and artificial radionuclides", in F. Ullmann (ed.), Ullmann's Encyclopedia of Industrial Chemistry, vol. 31, Wiley-VCH, Weinheim, pp. 89–117, doi:10.1002/14356007.o22_o15.
- King R. B. 1995, Inorganic Chemistry of Main Group Elements, Wiley-VCH, New York, ISBN 978-1-56081-679-9.
- Kolthoff I. M. & Elving P. J. FR 1964, Treatise on Analytical Chemistry, part II, vol. 6, Interscience Encyclopedia, New York, ISBN 978-0-07-038685-3.
- Korenman I. M. 1959, "Regularities in properties of thallium", Journal of General Chemistry of the USSR, English translation, Consultants Bureau, New York, vol. 29, no. 2, pp. 1366–90, ISSN 0022-1279.
- Kozin L. F. & Hansen S. C. 2013, Mercury Handbook: Chemistry, Applications and Environmental Impact, RSC Publishing, Cambridge, ISBN 978-1-84973-409-7.
- Kumar R., Srivastava P. K., Srivastava S. P. 1994, "Leaching of heavy metals (Cr, Fe, and Ni) from stainless steel utensils in food simulates and food materials", Bulletin of Environmental Contamination and Toxicology, vol. 53, no. 2, doi:10.1007/BF00192942, pp. 259–266.
- Lach K., Steer B., Gorbunov B., Mička V. & Muir R. B. 2015, "Evaluation of exposure to airborne heavy metals at gun shooting ranges", The Annals of Occupational Hygiene, vol. 59, no. 3, pp. 307–323, doi:10.1093/annhyg/meu097.
- Landis W., Sofield R. & Yu M-H. 2010, Introduction to Environmental Toxicology: Molecular Substructures to Ecological Landscapes, 4th ed., CRC Press, Boca Raton, Florida, ISBN 978-1-4398-0411-7.
- Lane T. W., Saito M. A., George G. N., Pickering, I. J., Prince R. C. & Morel F. M. M. 2005, "Biochemistry: A cadmium enzyme from a marine diatom", Nature, vol. 435, no. 7038, p. 42, doi:10.1038/435042a.
- Lee J. D. 1996, Concise Inorganic Chemistry, 5th ed., Blackwell Science, Oxford, ISBN 978-0-632-05293-6.
- Leeper G. W. 1978, Managing the Heavy Metals on the Land Marcel Dekker, New York, ISBN 0-8247-6661-X.
- Lemly A. D. 1997, "A teratogenic deformity index for evaluating impacts of selenium on fish populations", Ecotoxicology and Environmental Safety, vol. 37, no. 3, pp. 259–266, doi:10.1006/eesa.1997.1554.
- Lide D. R. (ed.) 2004, CRC Handbook of Chemistry and Physics, 85th ed., CRC Press, Boca Raton, Florida, ISBN 978-0-8493-0485-9.
- Liens J. 2010, "Heavy metals as pollutants", in B. Warf (ed.), Encyclopaedia of Geography, Sage Publications, Thousand Oaks, California, pp. 1415–1418, ISBN 978-1-4129-5697-0.
- Lima E., Guerra R., Lara V. & Guzmán A. 2013, "Gold nanoparticles as efficient antimicrobial agents for Escherichia coli and Salmonella typhi " Chemistry Central, vol. 7:11, doi:10.1186/1752-153X-7-11 PMID 23331621 PMC 3556127.
- Litasov K. D. & Shatskiy A. F. 2016, "Composition of the Earth's core: A review", Russian Geology and Geophysics, vol. 57, no. 1, pp. 22–46, doi:10.1016/j.rgg.2016.01.003.
- Livesey A. 2012, Advanced Motorsport Engineering, Routledge, London, ISBN 978-0-7506-8908-3.
- Livingston R. A. 1991, "Influence of the Environment on the Patina of the Statue of Liberty", Environmental Science & Technology, vol. 25, no. 8, pp. 1400–1408, doi:10.1021/es00020a006.
- Longo F. R. 1974, General Chemistry: Interaction of Matter, Energy, and Man, McGraw-Hill, New York, ISBN 978-0-07-038685-3.
- Love M. 1998, Phasing Out Lead from Gasoline: Worldwide Experience and Policy Implications, World Bank Technical Paper volume 397, The World Bank, Washington DC, ISBN 0-8213-4157-X.
- Lyman W. J. 1995, "Transport and transformation processes", in Fundamentals of Aquatic Toxicology, G. M. Rand (ed.), Taylor & Francis, London, pp. 449–492, ISBN 978-1-56032-090-6.
- Macintyre J. E. 1994, Dictionary of inorganic compounds, supplement 2, Dictionary of Inorganic Compounds, vol. 7, Chapman & Hall, London, ISBN 978-0-412-49100-9.
- MacKay K. M., MacKay R. A. & Henderson W. 2002, Introduction to Modern Inorganic Chemistry, 6th ed., Nelson Thornes, Cheltenham, ISBN 978-0-7487-6420-4.
- Magee R. J. 1969, Steps to Atomic Power, Cheshire for La Trobe University, Melbourne.
- Magill F. N. I (ed.) 1992, Magill's Survey of Science, Physical Science series, vol. 3, Salem Press, Pasadena, ISBN 978-0-89356-621-0.
- Martin M. H. & Coughtrey P. J. 1982, Biological Monitoring of Heavy Metal Pollution, Applied Science Publishers, London, ISBN 978-0-85334-136-9.
- Massarani M. 2015, "Brazilian mine disaster releases dangerous metals," Chemistry World, November 2015, accessed 16 April 2016.
- Masters C. 1981, Homogenous Transition-metal Catalysis: A Gentle Art, Chapman and Hall, London, ISBN 978-0-412-22110-1.
- Matyi R. J. & Baboian R. 1986, "An X-ray Diffraction Analysis of the Patina of the Statue of Liberty", Powder Diffraction, vol. 1, no. 4, pp. 299–304, doi:10.1017/S0885715600011970.
- McColm I. J. 1994, Dictionary of Ceramic Science and Engineering, 2nd ed., Springer Science+Business Media, New York, ISBN 978-1-4419-3235-8.
- McCurdy R. M. 1975, Qualities and quantities: Preparation for College Chemistry, Harcourt Brace Jovanovich, New York, ISBN 978-0-15-574100-3.
- McLemore V. T. (ed.) 2008, Basics of Metal Mining Influenced Water, vol. 1, Society for Mining, Metallurgy, and Exploration, Littleton, Colorado, ISBN 978-0-87335-259-8.
- McQueen K. G. 2009, Regolith geochemistry, in K. M. Scott & C. F. Pain (eds), Regolith Science, CSIRO Publishing, Collingwood, Victoria, ISBN 978-0-643-09396-6.
- Mellor J. W. 1924, A comprehensive Treatise on Inorganic and Theoretical Chemistry, vol. 5, Longmans, Green and Company, London.
- Moore J. W. & Ramamoorthy S. 1984, Heavy Metals in Natural Waters: Applied Monitoring and Impact Assessment, Springer Verlag, New York, ISBN 978-1-4612-9739-0.
- Morris C. G. 1992, Academic Press Dictionary of Science and Technology, Harcourt Brace Jovanovich, San Diego, ISBN 978-0-12-200400-1.
- Morstein J. H. 2005, "Fat Man", in E. A. Croddy & Y. Y. Wirtz (eds), Weapons of Mass Destruction: An Encyclopedia of Worldwide Policy, Technology, and History, ABC-CLIO, Santa Barbara, California, ISBN 978-1-85109-495-0.
- Moselle B. (ed.) 2005, 2004 National Home Improvement Estimator, Craftsman Book Company, Carlsbad, California, ISBN 978-1-57218-150-2.
- Naja G. M. & Volesky B. 2009, "Toxicity and sources of Pb, Cd, Hg, Cr, As, and radionuclides", in L. K. Wang, J. P. Chen, Y. Hung & N. K. Shammas, Heavy Metals in the Environment, CRC Press, Boca Raton, Florida, ISBN 978-1-4200-7316-4.
- Nakbanpote W., Meesungneon O. & Prasad M. N. V. 2016, "Potential of ornamental plants for phytoremediation of heavy metals and income generation", in M. N. V. Prasad (ed.), Bioremediation and Bioeconomy, Elsevier, Amsterdam, pp. 179–218, ISBN 978-0-12-802830-8.
- Nathans M. W. 1963, Elementary Chemistry, Prentice Hall, Englewood Cliffs, New Jersey.
- National Materials Advisory Board 1971, Trends in the Use of Depleted Uranium, National Academy of Sciences – National Academy of Engineering, Washington DC.
- National Materials Advisory Board 1973, Trends in Usage of Tungsten, National Academy of Sciences – National Academy of Engineering, Washington DC.
- National Organization for Rare Disorders 2015, Heavy metal poisoning, accessed 3 March 2016.
- Natural Resources Canada 2015, "Generation of the Earth's magnetic field", accessed 30 August 2016.
- Nieboer E. & Richardson D. 1978, "Lichens and 'heavy metals' ", International Lichenology Newsletter, vol. 11, no. 1, pp. 1–3.
- Nieboer E. & Richardson D. H. S. 1980, "The replacement of the nondescript term 'heavy metals' by a biologically and chemically significant classification of metal ions", Environmental Pollution Series B, Chemical and Physical, vol. 1, no. 1, pp. 3–26, doi:10.1016/0143-148X(80)90017-8.
- Nzierżanowski K. & Gawroński S. W. 2012, "Heavy metal concentration in plants growing on the vicinity of railroad tracks: a pilot study", Challenges of Modern Technology, vol. 3, no. 1, pp. 42–45, ISSN 2353-4419, accessed 21 August 2016.
- Ohlendorf H. M. 2003, "Ecotoxicology of selenium", in D. J. Hoffman, B. A. Rattner, G. A. Burton & J. Cairns, Handbook of Ecotoxicology, 2nd ed., Lewis Publishers, Boca Raton, pp. 466–491, ISBN 978-1-56670-546-2.
- Ondreička R., Kortus J. & Ginter E. 1971, "Aluminium, its absorption, distribution, and effects on phosphorus metabolism", in S. C. Skoryna & D. Waldron-Edward (eds), Intestinal Absorption of Metal Ions, Trace Elements and Radionuclides, Pergamon press, Oxford.
- Ong K. L., Tan T. H. & Cheung W. L. 1997, "Potassium permanganate poisoning—a rare cause of fatal poisoning", Journal of Accident & Emergency Medicine, vol. 14, no. 1, pp. 43–45, PMC 1342846.
- Oxford English Dictionary 1989, 2nd ed., Oxford University Press, Oxford, ISBN 978-0-19-861213-1.
- Pacheco-Torgal F., Jalali S. & Fucic A. (eds) 2012, Toxicity of building materials, Woodhead Publishing, Oxford, ISBN 978-0-85709-122-2.
- Padmanabhan T. 2001, Theoretical Astrophysics, vol. 2, Stars and Stellar Systems, Cambridge University Press, Cambridge, ISBN 978-0-521-56241-6.
- Pan W. & Dai J. 2015, "ADS based on linear accelerators", in W. Chao & W. Chou (eds), Reviews of accelerator science and technology, vol. 8, Accelerator Applications in Energy and Security, World Scientific, Singapore, pp. 55–76, ISBN 981-3108-89-4.
- Parish R. V. 1977, The Metallic Elements, Longman, New York, ISBN 978-0-582-44278-8.
- Perry J. & Vanderklein E. L. Water Quality: Management of a Natural Resource, Blackwell Science, Cambridge, Massachusetts ISBN 0-86542-469-1.
- Pickering N. C. 1991, The Bowed String: Observations on the Design, Manufacture, Testing and Performance of Strings for Violins, Violas and Cellos, Amereon, Mattituck, New York.
- Podosek F. A. 2011, "Noble gases", in H. D. Holland & K. K. Turekian (eds), Isotope Geochemistry: From the Treatise on Geochemistry, Elsevier, Amsterdam, pp. 467–492, ISBN 978-0-08-096710-3.
- Podsiki C. 2008, "Heavy metals, their salts, and other compounds", AIC News, November, special insert, pp. 1–4.
- Preschel J. July 29, 2005, "Green bullets not so eco-friendly", CBS News, accessed 18 March 2016.
- Preuss P. 17 July 2011, "What keeps the Earth cooking?," Berkeley Lab, accessed 17 July 2016.
- Prieto C. 2011, The Adventures of a Cello: Revised Edition, with a New Epilogue, University of Texas Press, Austin, ISBN 978-0-292-72393-1
- Raghuram P., Soma Raju I. V. & Sriramulu J. 2010, "Heavy metals testing in active pharmaceutical ingredients: an alternate approach", Pharmazie, vol. 65, no. 1, pp. 15–18, doi:10.1691/ph.2010.9222.
- Rainbow P. S. 1991, "The biology of heavy metals in the sea", in J. Rose (ed.), Water and the Environment, Gordon and Breach Science Publishers, Philadelphia, pp. 415–432, ISBN 978-2-88124-747-7.
- Rand G. M., Wells P. G. & McCarty L. S. 1995, "Introduction to aquatic toxicology", in G. M. Rand (ed.), Fundamentals of Aquatic Toxicology: Effects, Environmental Fate and Risk Assessment, 2nd ed., Taylor & Francis, London, pp. 3–70, ISBN 978-1-56032-090-6.
- Rankin W. J. 2011, Minerals, Metals and Sustainability: Meeting Future Material Needs, CSIRO Publishing, Collingwood, Victoria, ISBN 978-0-643-09726-1.
- Rasic-Milutinovic Z. & Jovanovic D. 2013, "Toxic metals", in M. Ferrante, G. Oliveri Conti, Z. Rasic-Milutinovic & D. Jovanovic (eds), Health Effects of Metals and Related Substances in Drinking Water, IWA Publishing, London, ISBN 978-1-68015-557-0.
- Raymond R. 1984, Out of the Fiery Furnace: The Impact of Metals on the History of Mankind, Macmillan, South Melbourne, ISBN 978-0-333-38024-6.
- Rebhandl W., Milassin A., Brunner L., Steffan I., Benkö T., Hörmann M., Burschen J. 2007, "In vitro study of ingested coins: Leave them or retrieve them?", Journal of Paediatric Surgery, vol. 42, no. 10, pp. 1729–1734, doi:10.1016/j.jpedsurg.2007.05.031.
- Rehder D. 2010, Chemistry in Space: From Interstellar Matter to the Origin of Life, Wiley-VCH, Weinheim, ISBN 978-3-527-32689-1.
- Renner H., Schlamp G., Kleinwächter I., Drost E., Lüchow H. M., Tews P., Panster P., Diehl M., Lang J., Kreuzer T., Knödler A., Starz K. A., Dermann K., Rothaut J., Drieselmann R., Peter C. & Schiele R. 2012, "Platinum Group Metals and compounds", in F. Ullmann (ed.), Ullmann's Encyclopedia of Industrial Chemistry, vol. 28, Wiley-VCH, Weinheim, pp. 317–388, doi:10.1002/14356007.a21_075.
- Reyes J. W. 2007, Environmental Policy as Social Policy? The Impact of Childhood Lead Exposure on Crime, National Bureau of Economic Research Working Paper 13097, accessed 16 October 2016.
- Ridpath I. (ed.) 2012, Oxford Dictionary of Astronomy, 2nd ed. rev., Oxford University Press, New York, ISBN 978-0-19-960905-5.
- Rockhoff H. 2012, America's Economic Way of War: War and the US Economy from the Spanish–American War to the Persian Gulf War, Cambridge University Press, Cambridge, ISBN 978-0-521-85940-0.
- Roe J. & Roe M. 1992, "World's coinage uses 24 chemical elements", World Coinage News, vol. 19, no. 4, pp. 24–25; no. 5, pp. 18–19.
- Russell A. M. & Lee K. L. 2005, Structure–Property Relations in Nonferrous Metals, John Wiley & Sons, Hoboken, New Jersey, ISBN 978-0-471-64952-6.
- Rusyniak D. E., Arroyo A., Acciani J., Froberg B., Kao L. & Furbee B. 2010, "Heavy metal poisoning: Management of intoxication and antidotes", in A. Luch (ed.), Molecular, Clinical and Environmental Toxicology, vol. 2, Birkhäuser Verlag, Basel, pp. 365–396, ISBN 978-3-7643-8337-4.
- Ryan J. 2012, Personal Financial Literacy, 2nd ed., South-Western, Mason, Ohio, ISBN 978-0-8400-5829-4.
- Samsonov G. V. (ed.) 1968, Handbook of the Physicochemical Properties of the Elements, IFI-Plenum, New York, ISBN 978-1-4684-6066-7.
- Sanders R. 2003, "Radioactive potassium may be major heat source in Earth's core," UCBerkelyNews, 10 December, accessed 17 July 20016.
- Schweitzer P. A. 2003, Metallic materials: Physical, Mechanical, and Corrosion properties, Marcel Dekker, New York, ISBN 978-0-8247-0878-8.
- Schweitzer G. K. & Pesterfield L. L. 2010, The Aqueous Chemistry of the Elements, Oxford University Press, Oxford, ISBN 978-0-19-539335-4.
- Scott R. M. 1989, Chemical Hazards in the Workplace, CRC Press, Boca Raton, Orlando, ISBN 978-0-87371-134-0.
- Scoullos M. (ed.), Vonkeman G. H., Thornton I. & Makuch Z. 2001, Mercury — Cadmium — Lead Handbook for Sustainable Heavy Metals Policy and Regulation, Kluwer Academic Publishers, Dordrecht, ISBN 978-1-4020-0224-3.
- Selinger B. 1978, Chemistry in the Market Place, 2nd ed., Australian National University Press, Canberra, ISBN 978-0-7081-0728-7.
- Seymour R. J. & O'Farrelly J. 2012, "Platinum Group Metals", Kirk-Other Encyclopaedia of Chemical Technology, John Wiley & Sons, New York, doi:10.1002/0471238961.1612012019052513.a01.pub3.
- Shaw B. P., Sahu S. K. & Mishra R. K. 1999, "Heavy metal induced oxidative damage in terrestrial plants", in M. N. V. Prased (ed.), Heavy Metal Stress in Plants: From Biomolecules to Ecosystems Springer-Verlag, Berlin, ISBN 978-3-540-40131-5.
- Shedd K. B. 2002, "Tungsten", Minerals Yearbook, United States Geological Survey.
- Sidgwick N. V. 1950, The Chemical Elements and their Compounds, vol. 1, Oxford University Press, London.
- Silva R. J. 2010, "Fermium, mendelevium, nobelium, and lawrencium", in L. R. Morss, N. Edelstein & J. Fuger (eds), The Chemistry of the Actinide and Transactinide Elements, vol. 3, 4th ed., Springer, Dordrecht, pp. 1621–1651, ISBN 978-94-007-0210-3.
- Spolek G. 2007, "Design and materials in fly fishing", in A. Subic (ed.), Materials in Sports Equipment, Volume 2, Woodhead Publishing, Abington, Cambridge, pp. 225–247, ISBN 978-1-84569-131-8.
- Stankovic S. & Stankocic A. R. 2013, "Bioindicators of toxic metals", in E. Lichtfouse, J. Schwarzbauer, D. Robert 2013, Green materials for energy, products and depollution, Springer, Dordrecht, ISBN 978-94-007-6835-2, pp. 151–228.
- State Water Control Resources Board 1987, Toxic substances monitoring program, issue 79, part 20 of the Water Quality Monitoring Report, Sacramento, California.
- Technical Publications 1953, Fire Engineering, vol. 111, p. 235, ISSN 0015-2587.
- The Minerals, Metals and Materials Society, Light Metals Division 2016, accessed 22 June 2016.
- The United States Pharmacopeia 1985, 21st revision, The United States Pharmacopeial Convention, Rockville, Maryland, ISBN 978-0-913595-04-6.
- Thorne P. C. L. & Roberts E. R. 1943, Fritz Ephraim Inorganic Chemistry, 4th ed., Gurney and Jackson, London.
- Tisza M. 2001, Physical Metallurgy for Engineers, ASM International, Materials Park, Ohio, ISBN 978-0-87170-725-3.
- Tokar E. J., Boyd W. A., Freedman J. H. & Wales M. P. 2013, "Toxic effects of metals", in C. D. Klaassen (ed.), Casarett and Doull's Toxicology: the Basic Science of Poisons, 8th ed., McGraw-Hill Medical, New York, ISBN 978-0-07-176923-5, accessed 9 September 2016 (subscription required).
- Tomasik P. & Ratajewicz Z. 1985, Pyridine metal complexes, vol. 14, no. 6A, The Chemistry of Heterocyclic Compounds, John Wiley & Sons, New York, ISBN 978-0-471-05073-5.
- Topp N. E. 1965, The Chemistry of the Rare-earth Elements, Elsevier Publishing Company, Amsterdam.
- Torrice M. 2016, "How lead ended up in Flint's tap water," Chemical & Engineering News, vol. 94, no. 7, pp. 26–27.
- Tretkoff E. 2006, "March 20, 1800: Volta describes the Electric Battery", APS News, This Month in Physics History, American Physical Society, accessed 26 August 2016.
- Uden P. C. 2005, 'Speciation of Selenium,' in R. Cornelis, J. Caruso, H. Crews & K. Heumann (eds), Handbook of Elemental Speciation II: Species in the Environment, Food, Medicine and Occupational Health, John Wiley & Sons, Chichester, pp. 346–65, ISBN 978-0-470-85598-0.
- United States Environmental Protection Agency 1988, Ambient Aquatic Life Water Quality Criteria for Antimony (III), draft, Office of Research and Development, Environmental Research Laboratories, Washington.
- United States Environmental Protection Agency 2014, Technical Fact Sheet–Tungsten, accessed 27 March 2016.
- United States Government 2014, Toxic Pollutant List, Code of Federal Regulations, 40 CFR 401.15., accessed 27 March 2016.
- Valkovic V. 1990, "Origin of trace element requirements by living matter", in B. Gruber & J. H. Yopp (eds), Symmetries in Science IV: Biological and biophysical systems, Plenum Press, New York, pp. 213–242, ISBN 978-1-4612-7884-9.
- VanGelder K. T. 2014, Fundamentals of Automotive Technology: Principles and Practice, Jones & Bartlett Learning, Burlington MA, ISBN 978-1-4496-7108-2.
- Venner M., Lessening M., Pankani D. & Strecker E. 2004, Identification of Research Needs Related to Highway Runoff Management, Transportation Research Board, Washington DC, ISBN 978-0-309-08815-2, accessed 21 August 2016.
- Venugopal B. & Luckey T. D. 1978, Metal Toxicity in Mammals, vol. 2, Plenum Press, New York, ISBN 978-0-306-37177-6.
- Vernon R. E. 2013, "Which elements are metalloids", Journal of Chemical Education, vol. 90, no. 12, pp. 1703–1707, doi:10.1021/ed3008457.
- Volesky B. 1990, Biosorption of Heavy Metals, CRC Press, Boca Raton, ISBN 978-0-8493-4917-1.
- von Gleich A. 2013, "Outlines of a sustainable metals industry", in A. von Gleich, R. U. Ayres & S. Gößling-Reisemann (eds), Sustainable Metals Management, Springer, Dordrecht, pp. 3–40, ISBN 978-1-4020-4007-8.
- von Zeerleder A. 1949, Technology of Light Metals, Elsevier Publishing Company, New York.
- Warth A. H. 1956, The Chemistry and Technology of Waxes, Reinhold Publishing Corporation, New York.
- Weart S. R. 1983, "The discovery of nuclear fission and a nuclear physics paradigm", in W. Shea (ed.), Otto Hahn and the Rise of Nuclear Physics, D. Reidel Publishing Company, Dordrecht, pp. 91–133, ISBN 978-90-277-1584-5.
- Weber D. J. & Rutula W. A. 2001, "Use of metals as microbicides in preventing infections in healthcare", in Disinfection, Sterilization, and Preservation, 5th ed., S. S. Block (ed.), Lippincott, Williams & Wilkins, Philadelphia, ISBN 978-0-683-30740-5.
- Weller G. 1976, Cleaning and Preservation of Coins and Medals, S. J. Durst, New York, ISBN 978-0-915262-03-8.
- White C. 2010, Projectile Dynamics in Sport: Principles and Applications, Routledge, London, ISBN 978-0-415-47331-6.
- Wiberg N. 2001, Inorganic Chemistry, Academic Press, San Diego, ISBN 978-0-12-352651-9.
- Wijayawardena M. A. A., Megharaj M. & Naidu R. 2016, "Exposure, toxicity, health impacts and bioavailability of heavy metal mixtures", in D. L. Sparks, Advances in Agronomy, vol. 138, pp. 175–234, Academic Press, London, ISBN 978-0-12-804774-3.
- Wingerson L. 1986, "America cleans up Liberty", New Scientist, 25 December/1 January 1987, pp. 31–35, accessed 1 October 2016.
- Wong M. Y., Hedley G. J., Xie G., Kölln L. S, Samuel I. D. W., Pertegaś A., Bolink H. J., Mosman-Colman, E., "Light-emitting electrochemical cells and solution-processed organic light-emitting diodes using small molecule organic thermally activated delayed fluorescence emitters", Chemistry of Materials, vol. 27, no. 19, pp. 6535–6542, doi:10.1021/acs.chemmater.5b03245.
- Wulfsberg G. 1987, Principles of Descriptive Inorganic Chemistry, Brooks/Cole Publishing Company, Monterey, California, ISBN 978-0-534-07494-4.
- Wulfsberg G. 2000, Inorganic Chemistry, University Science Books, Sausalito, California, ISBN 978-1-891389-01-6.
- Yadav J. S., Antony A., Subba Reddy, B. V. 2012, "Bismuth(III) salts as synthetic tools in organic transformations", in T. Ollevier (ed.), Bismuth-mediated Organic Reactions, Topics in Current Chemistry 311, Springer, Heidelberg, ISBN 978-3-642-27238-7.
- Yang D. J., Jolly W. L. & O'Keefe A. 1977, "Conversion of hydrous germanium(II) oxide to germynyl sesquioxide, (HGe)2O3", 'Inorganic Chemistry, vol. 16, no. 11, pp. 2980–2982, doi:10.1021/ic50177a070.
- Yousif N. 2007, Geochemistry of stream sediment from the state of Colorado using NURE data, ETD Collection for the University of Texas, El Paso, paper AAI3273991.
Definition and usage
- Ali H. & Khan E. 2017, "What are heavy metals? long-standing controversy over the scientific use of the term 'heavy metals'—proposal of a comprehensive definition", Toxicological & Environmental Chemistry, pp. 1–25, doi:10.1080/02772248.2017.1413652. Suggests defining heavy metals as "naturally occurring metals having atomic number (Z) greater than 20 and an elemental density greater than 5 g cm−3".
- Duffus J. H. 2002, "'Heavy metals'—A meaningless term?", Pure and Applied Chemistry, vol. 74, no. 5, pp. 793–807, doi:10.1351/pac200274050793. Includes a survey of the term's various meanings.
- Hawkes S. J. 1997, "What is a "heavy metal"?", Journal of Chemical Education, vol. 74, no. 11, p. 1374, doi:10.1021/ed074p1374. A chemist's perspective.
- Hübner R., Astin K. B. & Herbert R. J. H. 2010, " 'Heavy metal'—time to move on from semantics to pragmatics?", Journal of Environmental Monitoring, vol. 12, pp. 1511–1514, doi:10.1039/C0EM00056F. Finds that, despite its lack of specificity, the term appears to have become part of the language of science.
Toxicity and biological role
- Baird C. & Cann M. 2012, Environmental Chemistry, 5th ed., chapter 12, "Toxic heavy metals", W. H. Freeman and Company, New York, ISBN 1-4292-7704-1. Discusses the use, toxicity, and distribution of Hg, Pb, Cd, As, and Cr.
- Nieboer E. & Richardson D. H. S. 1980, "The replacement of the nondescript term 'heavy metals' by a biologically and chemically significant classification of metal ions", Environmental Pollution Series B, Chemical and Physical, vol. 1, no. 1, pp. 3–26, doi:10.1016/0143-148X(80)90017-8. A widely cited paper, focusing on the biological role of heavy metals.
- Hadhazy A. 2016, "Galactic 'gold mine' explains the origin of nature's heaviest elements", Science Spotlights, 10 May, accessed 11 July 2016
- Koehler C. S. W. 2001, "Heavy metal medicine", Chemistry Chronicles, American Chemical Society, accessed 11 July 2016
- Morowitz N. 2006, "The heavy metals," Modern Marvels, season 12, episode 14, HistoryChannel.com
- Öhrström L. 2014, "Tantalum oxide", Chemistry World, 24 September, accessed 4 October 2016. The author explains how tantalum(V) oxide banished brick-sized mobile phones. Also available as a podcast.
Media related to Heavy metals at Wikimedia Commons