Distonic ions are chemical species that contain two ionic charges on the same molecule separated by two or more carbon or heteroatoms. Distonic radical ions are unique due to the fact that its charges and radical sites are in different locations (on separate atoms ), unlike regular radicals where the formal charge and unpaired electron are in the same location. These molecular species are created when ionization takes place with either zwitterions or diradicals; ultimately, a neutral molecule loses an electron. Through experimental research distonic radicals have been found to be extremely stable gas phase ions and can be separated into different classes depending on the inherent features of the charged portion of the ion.
In 1984 scientists Bouma, Radom and Yates originated the term through extensive experimental research but they were not the first to deal with distonic ions. Experiments date back to the 1970s with Gross and McLafferty who were the first to propose the idea of such a species.
There are several efficient techniques in place that can detect the presence of distonic ions, however when deciding on which method is most appropriate, one must keep in mind the ions internal energy and lifespan. Collisions between ions and neutrally charged molecules allow an individual to detect the location of the radical and charge site in order to ensure the ion is indeed not just a regular radical ion. When a molecule is ionized and can structurally be classified as a distonic ion, the molecules kinetics and thermodynamic properties have been greatly altered. However, additional chemical properties are based on the reactions of the central excited ions. Mass spectrometry techniques are used to study their chemistry.
Distonic ions have been extensively examined due to their unique behavior and how common they can occur. Through the obtained data, it has been shown that in most cases distonic ions have corresponding bonding arrangement as the original molecule before ionization occurred. However data has also shown that distonic ions possess less stability than before ionization occurred; having said that, this does not take away from the fact that distonic ions are considered stable ions and have caught many scientist attention because they possess more stability than its traditional isomer. Challenges do arise when trying to decipher the functions of the charge and radical site because distonic ions are limited to elementary reactions such as unimolecular reactions involving highly excited and short-lived species.
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