# Dihydrogen cation

The **dihydrogen cation** or **hydrogen molecular ion** is a cation (positive ion) with formula **H ^{+}_{2}**. It consists of two hydrogen nuclei (protons) sharing a single electron. It is the simplest molecular ion.

The ion can be formed from the ionization of a neutral hydrogen molecule H^{}_{2}. It is commonly formed in molecular clouds in space, by the action of cosmic rays.

The dihydrogen cation is of great historical and theoretical interest because, having only one electron, the equations of quantum mechanics that describe its structure can be solved in a relatively straightforward way. The first such solution was derived by Ø. Burrau in 1927,[1] just one year after the wave theory of quantum mechanics was published.

## Physical properties

Bonding in H^{+}_{2} can be described as a covalent one-electron bond, which has a formal bond order of one half.[2]

## Quantum mechanical analysis

The Schrödinger equation (in the clamped-nuclei approximation) for this cation can be solved in a relatively straightforward way due to the lack of electron–electron repulsion (electron correlation). The analytical solutions for the electronic energy eigenvalues are a *generalization* of the Lambert W function[6] which can be obtained using a computer algebra system within an experimental mathematics approach. Consequently, it is included as an example in most quantum chemistry textbooks.

The first successful quantum mechanical treatment of H^{+}_{2} was published by the Danish physicist Øyvind Burrau in 1927,[1] just one year after the publication of wave mechanics by Erwin Schrödinger. Earlier attempts using the old quantum theory had been published in 1922 by Karel Niessen[7] and Wolfgang Pauli,[8] and in 1925 by Harold Urey.[9] In 1928, Linus Pauling published a review putting together the work of Burrau with the work of Walter Heitler and Fritz London on the hydrogen molecule.[10]

### Clamped-nuclei (Born-Oppenheimer) approximation

The electronic Schrödinger wave equation for the hydrogen molecular ion H^{+}_{2} with two fixed nuclear centers, labeled *A* and *B*, and one electron can be written as

where *V* is the electron-nuclear Coulomb potential energy function:

and *E* is the (electronic) energy of a given quantum mechanical state (eigenstate), with the electronic state function *ψ* = *ψ*(**r**) depending on the spatial coordinates of the electron. An additive term 1/*R*, which is constant for fixed internuclear distance *R*, has been omitted from the potential *V*, since it merely shifts the eigenvalue. The distances between the electron and the nuclei are denoted *r _{a}* and

*r*. In atomic units (

_{b}*ħ*=

*m*=

*e*= 4π

*ε*

_{0}= 1) the wave equation is

We choose the midpoint between the nuclei as the origin of coordinates. It follows from general symmetry principles that the wave functions can be characterized by their symmetry behavior with respect to the point group inversion operation * i* (

**r**↦ −

**r**). There are wave functions

*ψ*

_{g}(

**r**), which are

*symmetric*with respect to

*, and there are wave functions*

**i***ψ*

_{u}(

**r**), which are

*antisymmetric*under this symmetry operation:

The suffixes *g* and *u* are from the German *gerade* and *ungerade*) occurring here denote the symmetry behavior under the point group inversion operation * i*. Their use is standard practice for the designation of electronic states of diatomic molecules, whereas for atomic states the terms

*even*and

*odd*are used. The ground state (the lowest state) of H

^{+}

_{2}is denoted X

^{2}Σ

^{+}

_{g}[11] or 1sσ

_{g}and it is gerade. There is also the first excited state A

^{2}Σ

^{+}

_{u}(2pσ

_{u}), which is ungerade.

Asymptotically, the (total) eigenenergies *E*_{g/u} for these two lowest lying states have the same asymptotic expansion in inverse powers of the internuclear distance *R*:[12]

The actual difference between these two energies is called the exchange energy splitting and is given by:[13]

which exponentially vanishes as the internuclear distance *R* gets greater. The lead term 4/*e**Re*^{−R} was first obtained by the Holstein–Herring method. Similarly, asymptotic expansions in powers of 1/*R* have been obtained to high order by Cizek *et al.* for the lowest ten discrete states of the hydrogen molecular ion (clamped nuclei case). For general diatomic and polyatomic molecular systems, the exchange energy is thus very elusive to calculate at large internuclear distances but is nonetheless needed for long-range interactions including studies related to magnetism and charge exchange effects. These are of particular importance in stellar and atmospheric physics.

The energies for the lowest discrete states are shown in the graph above. These can be obtained to within arbitrary accuracy using computer algebra from the generalized Lambert W function (see eq. (3) in that site and the reference of Scott, Aubert-Frécon, and Grotendorst) but were obtained initially by numerical means to within double precision by the most precise program available, namely ODKIL.[14] The red solid lines are ^{2}Σ^{+}_{g} states. The green dashed lines are ^{2}Σ^{+}_{u} states. The blue dashed line is a ^{2}Π_{u} state and the pink dotted line is a ^{2}Π_{g} state. Note that although the generalized Lambert W function eigenvalue solutions supersede these asymptotic expansions, in practice, they are most useful near the bond length. These solutions are possible because the partial differential equation of the wave equation here separates into two coupled ordinary differential equations using prolate spheroidal coordinates.

The complete Hamiltonian of H^{+}_{2} (as for all centrosymmetric molecules) does not commute with the point group inversion operation * i* because of the effect of the nuclear hyperfine Hamiltonian. The nuclear hyperfine Hamiltonian can mix the rotational levels of

*and*

**g***electronic states (called*

**u***-*

**ortho***mixing) and give rise to*

**para***-*

**ortho***transitions[15][16]*

**para**## Occurrence in space

### Formation

The dihydrogen ion is formed in nature by the interaction of cosmic rays and the hydrogen molecule. An electron is knocked off leaving the cation behind.[17]

- H
_{2}+ cosmic ray → H^{+}_{2}+ e^{−}+ cosmic ray.

Cosmic ray particles have enough energy to ionize many molecules before coming to a stop.

The ionization energy of the hydrogen molecule is 15.603 eV. High speed electrons also cause ionization of hydrogen molecules with a peak cross section around 50 eV. The peak cross section for ionization for high speed protons is 70000 eV with a cross section of 2.5×10^{−16} cm^{2}. A cosmic ray proton at lower energy can also strip an electron off a neutral hydrogen molecule to form a neutral hydrogen atom and the dihydrogen cation, (p^{+} + H_{2} → H + H^{+}_{2}) with a peak cross section at around 8000 eV of 8×10^{−16} cm^{2}.[18]

An artificial plasma discharge cell can also produce the ion.

### Destruction

In nature the ion is destroyed by reacting with other hydrogen molecules:

- H
^{+}_{2}+ H_{2}→ H^{+}_{3}+ H.

## See also

- Symmetry of diatomic molecules
- Dirac Delta function model (one-dimensional version of H
^{+}_{2}) - Di-positronium
- Euler's three-body problem (classical counterpart)
- Few-body systems
- Helium atom
- Helium hydride ion
- Trihydrogen cation
- Triatomic hydrogen
- Lambert W function
- Molecular astrophysics
- Holstein–Herring method
- Three-body problem
- List of quantum-mechanical systems with analytical solutions

## References

- Burrau, Ø. (1927). "Berechnung des Energiewertes des Wasserstoffmolekel-Ions (H
^{+}_{2}) im Normalzustand".*Danske Vidensk. Selskab. Math.-fys. Meddel.*(in German). M 7:14: 1–18.

Burrau, Ø. (1927). "The calculation of the Energy value of Hydrogen molecule ions (H^{+}_{2}) in their normal position" (PDF).*Naturwissenschaften*(in German).**15**(1): 16–7. Bibcode:1927NW.....15...16B. doi:10.1007/BF01504875. - Clark R. Landis; Frank Weinhold (2005).
*Valency and bonding: a natural bond orbital donor-acceptor perspective*. Cambridge, UK: Cambridge University Press. pp. 91–92. ISBN 978-0-521-83128-4. - Dario Bressanini, Massimo Mella, Gabriele Morosi, Chemical Physics Letters 272 (1997) 370-375; https://doi.org/10.1016/S0009-2614(97)00571-X
- Csaba Fábri, Gábor Czakó, Gyula Tasi, and Attila G. Császár (2009): "Adiabatic Jacobi corrections on the vibrational energy levels of H+

2 isotopologues".*Journal of Chemical Physics*, volume 130, issue 13, pages 134314. doi:10.1063/1.3097327 - Liam H. Scarlett, Mark C. Zammit, Dmitry V. Fursa, and Igor Bray (2017): "Kinetic-energy release of fragments from electron-impact dissociation of the molecular hydrogen ion and its isotopologues".
*Physical Reviews A*, volume 96, page 022706. doi:10.1103/PhysRevA.96.022706 - Scott, T. C.; Aubert-Frécon, M.; Grotendorst, J. (2006). "New Approach for the Electronic Energies of the Hydrogen Molecular Ion".
*Chem. Phys*.**324**(2–3): 323–338. arXiv:physics/0607081. Bibcode:2006CP....324..323S. doi:10.1016/j.chemphys.2005.10.031. - Karel F. Niessen
*Zur Quantentheorie des Wasserstoffmolekülions*, doctoral dissertation, University of Utrecht, Utrecht: I. Van Druten (1922) as cited in Mehra, Volume 5, Part 2, 2001, p. 932. - Pauli W (1922). "Über das Modell des Wasserstoffmolekülions".
*Annalen der Physik*.**373**(11): 177–240. doi:10.1002/andp.19223731101. Extended doctoral dissertation; received 4 March 1922, published in issue No. 11 of 3 August 1922. - Urey HC (October 1925). "The Structure of the Hydrogen Molecule Ion".
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*Molecular Spectra and Molecular Structure IV. Constants of Diatomic Molecules*. New York: Van Nostrand Reinhold. - Čížek, J.; Damburg, R. J.; Graffi, S.; Grecchi, V.; Harrel II, E. M.; Harris, J. G.; Nakai, S.; Paldus, J.; Propin, R. Kh.; Silverstone, H. J. (1986). "1/
*R*expansion for H^{+}_{2}: Calculation of exponentially small terms and asymptotics".*Phys. Rev. A*.**33**: 12–54. Bibcode:1986PhRvA..33...12C. doi:10.1103/PhysRevA.33.12. - Scott, T. C.; Dalgarno, A.; Morgan, J. D., III (1991). "Exchange Energy of H
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*J. Phys. B*.**22**(5): 697–712. Bibcode:1989JPhB...22..697H. doi:10.1088/0953-4075/22/5/003. - Pique, J. P.; et al. (1984). "Hyperfine-Induced Ungerade-Gerade Symmetry Breaking in a Homonuclear Diatomic Molecule near a Dissociation Limit:
^{127}I_{2}at the^{2}P_{3/2}−^{2}P_{1/2}Limit".*Phys. Rev. Lett*.**52**(4): 267–269. Bibcode:1984PhRvL..52..267P. doi:10.1103/PhysRevLett.52.267. - Critchley, A. D. J.; et al. (2001). "Direct Measurement of a Pure Rotation Transition in H
^{+}_{2}".*Phys. Rev. Lett*.**86**(9): 1725–1728. Bibcode:2001PhRvL..86.1725C. doi:10.1103/PhysRevLett.86.1725. - Herbst, E. (2000). "The Astrochemistry of H
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